caa a22 4500 378903608 CHVBK 20180305123524.0 cr unu---uuuuu 161128e20041201xx s 000 0 eng 10.1515/epoly.2004.4.1.803 doi (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.803 Synthesis and characterization of 1,4-diazophenylenebridged Cu-phthalocyanine polymer [Elektronische Daten] [Cemil Alkan, Leyla Aras, Güngör Gündüz] A novel type of phthalocyanine polymer, 1,4-diazophenylene-bridged Cuphthalocyanine, was prepared from the diazonium salt of diaminobenzene and Cu(II) 1,8,15,22-tetraaminophthalocyanine. The polymer is partially soluble in tetrahydrofuran, dichloromethane, and dimethylformamide. Characterization of the polymer was performed by IR and UV-visible spectroscopy, X-ray diffraction, ash analysis, viscometry, differential scanning calorimetry and thermogravimetric analysis. The molecular weight of the soluble part of the polymer was determined by ebullioscopy. Electrical conductivity of the polymer and its doped samples were determined by the 4-probe technique. It was found that the electrical conductivity increased up to 10-4 S/cm after doping. The redox behaviour of the polymer was investigated utilizing cyclic voltammetry. © 2013 by Walter de Gruyter GmbH & Co. Alkan Cemil Middle East Technical University, Department of Chemistry, 06531 Ankara, Turkey; Fax 090 312 210 1280 aut Aras Leyla Middle East Technical University, Department of Chemistry, 06531 Ankara, Turkey; Fax 090 312 210 1280 aut Gündüz Güngör Middle East Technical University, Department of Chemical Engineering, 06531 Ankara, Turkey aut e-Polymers De Gruyter 4/1(2004-12-01), 803-812 2197-4586 4:1<803 2004 4 epoly https://doi.org/10.1515/epoly.2004.4.1.803 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1515/epoly.2004.4.1.803 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Alkan Cemil Middle East Technical University, Department of Chemistry, 06531 Ankara, Turkey; Fax 090 312 210 1280 aut NATIONALLICENCE 700 1- Aras Leyla Middle East Technical University, Department of Chemistry, 06531 Ankara, Turkey; Fax 090 312 210 1280 aut NATIONALLICENCE 700 1- Gündüz Güngör Middle East Technical University, Department of Chemical Engineering, 06531 Ankara, Turkey aut NATIONALLICENCE 773 0- e-Polymers De Gruyter 4/1(2004-12-01), 803-812 2197-4586 4:1<803 2004 4 epoly CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter