Nafion-layered silicate nanocomposite membrane for fuel cell application

Verfasser / Beitragende:
[Jean-Michel Thomassin, Christophe Pagnoulle, Didier Bizzari, Giuseppe Caldarella, Albert Germain, Robert Jérôme]
Ort, Verlag, Jahr:
2004
Enthalten in:
e-Polymers, 4/1(2004-12-01), 182-194
Format:
Artikel (online)
ID: 378903659
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024 7 0 |a 10.1515/epoly.2004.4.1.182  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.182 
245 0 0 |a Nafion-layered silicate nanocomposite membrane for fuel cell application  |h [Elektronische Daten]  |c [Jean-Michel Thomassin, Christophe Pagnoulle, Didier Bizzari, Giuseppe Caldarella, Albert Germain, Robert Jérôme] 
520 3 |a Direct methanol fuel cells (DMFCs) using a proton exchange membrane as electrolyte is an attractive option for electricity generation. The most widely used membrane in the DMFC system is based on a perfluorinated polymer bearing sulfonic acid functions like Nafion ®. The latter combines chemical, mechanical and thermal stability and high protonic conductivity but shows elevated methanol permeability. We propose the preparation of a novel type of hybrid membranes to tentatively solve this problem. This innovative material results from the homogeneous dispersion of a nano-scaled inorganic filler within Nafion. The filler consists of stacks of negatively charged alumino-silicate layers (Cloisite), with a positive counter-ion in the interlamellar space. The purpose of the addition of this filler is to decrease methanol diffusion through the polymer membrane without decreasing too much the ionic conductivity. 
540 |a © 2013 by Walter de Gruyter GmbH & Co. 
700 1 |a Thomassin  |D Jean-Michel  |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497  |4 aut 
700 1 |a Pagnoulle  |D Christophe  |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497  |4 aut 
700 1 |a Bizzari  |D Didier  |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435  |4 aut 
700 1 |a Caldarella  |D Giuseppe  |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435  |4 aut 
700 1 |a Germain  |D Albert  |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435  |4 aut 
700 1 |a Jérôme  |D Robert  |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Thomassin  |D Jean-Michel  |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Pagnoulle  |D Christophe  |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Bizzari  |D Didier  |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Caldarella  |D Giuseppe  |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Germain  |D Albert  |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Jérôme  |D Robert  |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t e-Polymers  |d De Gruyter  |g 4/1(2004-12-01), 182-194  |x 2197-4586  |q 4:1<182  |1 2004  |2 4  |o epoly 
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