Nafion-layered silicate nanocomposite membrane for fuel cell application
Gespeichert in:
Verfasser / Beitragende:
[Jean-Michel Thomassin, Christophe Pagnoulle, Didier Bizzari, Giuseppe Caldarella, Albert Germain, Robert Jérôme]
Ort, Verlag, Jahr:
2004
Enthalten in:
e-Polymers, 4/1(2004-12-01), 182-194
Format:
Artikel (online)
Online Zugang:
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.182 |2 doi |
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| 245 | 0 | 0 | |a Nafion-layered silicate nanocomposite membrane for fuel cell application |h [Elektronische Daten] |c [Jean-Michel Thomassin, Christophe Pagnoulle, Didier Bizzari, Giuseppe Caldarella, Albert Germain, Robert Jérôme] |
| 520 | 3 | |a Direct methanol fuel cells (DMFCs) using a proton exchange membrane as electrolyte is an attractive option for electricity generation. The most widely used membrane in the DMFC system is based on a perfluorinated polymer bearing sulfonic acid functions like Nafion ®. The latter combines chemical, mechanical and thermal stability and high protonic conductivity but shows elevated methanol permeability. We propose the preparation of a novel type of hybrid membranes to tentatively solve this problem. This innovative material results from the homogeneous dispersion of a nano-scaled inorganic filler within Nafion. The filler consists of stacks of negatively charged alumino-silicate layers (Cloisite), with a positive counter-ion in the interlamellar space. The purpose of the addition of this filler is to decrease methanol diffusion through the polymer membrane without decreasing too much the ionic conductivity. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Thomassin |D Jean-Michel |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497 |4 aut | |
| 700 | 1 | |a Pagnoulle |D Christophe |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497 |4 aut | |
| 700 | 1 | |a Bizzari |D Didier |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435 |4 aut | |
| 700 | 1 | |a Caldarella |D Giuseppe |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435 |4 aut | |
| 700 | 1 | |a Germain |D Albert |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435 |4 aut | |
| 700 | 1 | |a Jérôme |D Robert |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497 |4 aut | |
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| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Thomassin |D Jean-Michel |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Pagnoulle |D Christophe |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Bizzari |D Didier |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Caldarella |D Giuseppe |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Germain |D Albert |u Laboratoire de Chimie Industrielle, Institut de Chimie B6, University of Liège, Sart Tilman, 4000 Liège, Belgium; Fax (32)4-3664435 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Jérôme |D Robert |u Center for Education and Research on Macromolecules (CERM), University of Liège, Sart-Tilman, B6, 4000 Liège, Belgium; Fax (32)4-3663497 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 182-194 |x 2197-4586 |q 4:1<182 |1 2004 |2 4 |o epoly | ||
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