Atom transfer radical polymerization of styrene initiated by the novel initiator N-bromosuccinimide
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.204 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.204 | ||
| 245 | 0 | 0 | |a Atom transfer radical polymerization of styrene initiated by the novel initiator N-bromosuccinimide |h [Elektronische Daten] |c [Wei Zhang, Xiulin Zhu, Jian Zhu] |
| 520 | 3 | |a Heterogeneous atom transfer radical polymerization of styrene initiated by N-bromosuccinimide in bulk was successfully carried out with CuBr/2,2'-bipyridine as the catalyst. The kinetics follow first order in monomer and molecular weights (polydispersities Mw/Mn = 1.23 - 1.66) increase linearly with monomer conversion, indicating the ‘living'/controlled nature of the polymerization. However, the number-average molecular weights were usually higher than the theoretical ones. That demonstrates the relatively low efficiency of the initiator, the causes of which are discussed. The obtained polystyrenes functionalized with α-α-pyrrolidine- 2,5-dionyl and ω-Br as the end groups were characterized by 1H NMR spectroscopy. They can be used as macroinitiators for chain extension reaction. A polymerization mechanism for this novel initiation system is proposed. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Zhang |D Wei |u School of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, P. R. of China; Fax 86-512-65112796 |4 aut | |
| 700 | 1 | |a Zhu |D Xiulin |u School of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, P. R. of China; Fax 86-512-65112796 |4 aut | |
| 700 | 1 | |a Zhu |D Jian |u School of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, P. R. of China; Fax 86-512-65112796 |4 aut | |
| 773 | 0 | |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 204-211 |x 2197-4586 |q 4:1<204 |1 2004 |2 4 |o epoly | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/epoly.2004.4.1.204 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/epoly.2004.4.1.204 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zhang |D Wei |u School of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, P. R. of China; Fax 86-512-65112796 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zhu |D Xiulin |u School of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, P. R. of China; Fax 86-512-65112796 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zhu |D Jian |u School of Chemistry & Chemical Engineering, Suzhou University, Suzhou 215006, P. R. of China; Fax 86-512-65112796 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 204-211 |x 2197-4586 |q 4:1<204 |1 2004 |2 4 |o epoly | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||