Synthesis and characterization of 4-chloromethylstyrene polymers containing bulky organosilicon groups
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| 024 | 7 | 0 | |a 10.1515/epoly.2004.4.1.153 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1515/epoly.2004.4.1.153 | ||
| 245 | 0 | 0 | |a Synthesis and characterization of 4-chloromethylstyrene polymers containing bulky organosilicon groups |h [Elektronische Daten] |c [Kazem Dindar Safa, Mirzaagha Babazadeh] |
| 520 | 3 | |a The homopolymer of 4-chloromethylstyrene and its copolymers with styrene (in 1:3 and 1:1 mole ratio) were synthesized by bulk and solution freeradical polymerisations, respectively, at 70±1°C using α,α'-azoisobutyronitrile as an initiator. Highly sterically hindered tris(trimethylsilyl)methyl (Tsi) substituents were then covalently linked to the obtained homopolymer and copolymers. The polymers were characterized by IR, 1H NMR and 13C NMR, differential scanning calorimetry (DSC) and gel permeation chromatography. DSC showed that incorporation of Tsi substituents in the side chains of homopolymer and copolymers increases the rigidity of the polymers and, subsequently, their glass transition temperature. | |
| 540 | |a © 2013 by Walter de Gruyter GmbH & Co. | ||
| 700 | 1 | |a Safa |D Kazem Dindar |u Faculty of Chemistry, Tabriz University, 51664 Tabriz, Iran; Fax +98 411 3340191 |4 aut | |
| 700 | 1 | |a Babazadeh |D Mirzaagha |u Faculty of Chemistry, Tabriz University, 51664 Tabriz, Iran; Fax +98 411 3340191 |4 aut | |
| 773 | 0 | |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 153-162 |x 2197-4586 |q 4:1<153 |1 2004 |2 4 |o epoly | |
| 856 | 4 | 0 | |u https://doi.org/10.1515/epoly.2004.4.1.153 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1515/epoly.2004.4.1.153 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Safa |D Kazem Dindar |u Faculty of Chemistry, Tabriz University, 51664 Tabriz, Iran; Fax +98 411 3340191 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Babazadeh |D Mirzaagha |u Faculty of Chemistry, Tabriz University, 51664 Tabriz, Iran; Fax +98 411 3340191 |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t e-Polymers |d De Gruyter |g 4/1(2004-12-01), 153-162 |x 2197-4586 |q 4:1<153 |1 2004 |2 4 |o epoly | ||
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| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||