caa a22 4500 378903780 CHVBK 20180305123524.0 cr unu---uuuuu 161128e20040501xx s 000 0 eng 10.1524/zpch.218.5.515.30502 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.5.515.30502 Determination of Basicities of Organic Solvents and Absolute Electrode Potentials (E0-Values) of Monovalent Ions in Organic Solvents based on Absolute Values of Gibbs Energies of Solvation of Single Ions [Elektronische Daten] [Ranjana Bhattacharyya, S. C. Lahiri] Single ion Gibbs energies of monovalent ions in fourteen solvents (water, methanol, NMF, PC, ethanol, n-propanol, iso-propanol, n-butanol, t-butanol, ethylene glycol, acetone, THF, 1,4-dioxan, acetonitrile) with or without (ion-dipole, ion-induced dipole, ion-quadrupole) interactions were determined. The basicity of the solvents was determined from the absolute values of ΔG0solvation(H+) or ΔG0solution(H+) based on single standard state utilising the modified Born equation suggested by Lahiri. The method involves no arbitrary assumptions. A single scale for the absolute electrode potentials (E0 values) has been determined based on calculated Gibbs energies of solvation or solution of single ions. Appropriation of Gibbs energies of solvation of electrolytes into single ion values is not possible. Gibbs energies of formation of electrolytes in solvents must be taken into consideration. Stabilisation energies of electrolytes (MX) in solvents akin to lattice energies in solids were determined. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Bhattacharyya Ranjana aut Lahiri S. C. aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/5/2004(2004-05-01), 515-550 0942-9352 218:5/2004<515 2004 218 zpch https://doi.org/10.1524/zpch.218.5.515.30502 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.5.515.30502 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bhattacharyya Ranjana aut NATIONALLICENCE 700 1- Lahiri S. C. aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/5/2004(2004-05-01), 515-550 0942-9352 218:5/2004<515 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter