Kinetics and Mechanism of the Mineral Acid Catalysed Reactions of Hydroxamic Acids
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| 024 | 7 | 0 | |a 10.1524/zpch.218.5.563.30505 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.218.5.563.30505 | ||
| 245 | 0 | 0 | |a Kinetics and Mechanism of the Mineral Acid Catalysed Reactions of Hydroxamic Acids |h [Elektronische Daten] |c [Kallol K. Ghosh, Jyoti Vaidya, Daliya Sinha] |
| 520 | 3 | |a There is currently a great deal of interest in the chemistry of hydroxamic acids. In recent years we have been studying the synthesis, structure and nucleophilicities of hydroxamic acids. This paper reports a kinetic study of reactivity of some hydroxamic acids RC(O)·N(OH)R′; R=C6H5·CH=CH, R′=4-CH3·C6H4 [p-tolylcinnamo hydroxamic acid]; R=C6H5, R′=4-CH3·C6H4 [p-tolylbenzo hydroxamic acid]; R=C6H5, R′=2-CH3·C6H4 [o-tolylbenzo hydroxamic acid] in aqueous mineral acids (HCl, HClO4 and H2SO4). The rate data of hydrolysis reaction revealed that the reactivity/stability sequence of the compounds is generally p-TBHA>o-TBHA>p-TCHA. An excess acidity analysis reveals that the reaction proceeds by nucleophilic attack of water molecule on the protonated substrate. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Ghosh |D Kallol K. |4 aut | |
| 700 | 1 | |a Vaidya |D Jyoti |4 aut | |
| 700 | 1 | |a Sinha |D Daliya |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/5/2004(2004-05-01), 563-574 |x 0942-9352 |q 218:5/2004<563 |1 2004 |2 218 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.218.5.563.30505 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.218.5.563.30505 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ghosh |D Kallol K. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Vaidya |D Jyoti |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Sinha |D Daliya |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/5/2004(2004-05-01), 563-574 |x 0942-9352 |q 218:5/2004<563 |1 2004 |2 218 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||