Electrical Conductances of Tetrabutylammonium Bromide, Sodium Tetraphenylborate and Sodium Bromide in 2-Ethoxyethanol in the Temperature Range 35-50°C
| LEADER | caa a22 4500 | ||
|---|---|---|---|
| 001 | 378903810 | ||
| 003 | CHVBK | ||
| 005 | 20180305123525.0 | ||
| 007 | cr unu---uuuuu | ||
| 008 | 161128e20040501xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1524/zpch.218.5.599.30503 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.218.5.599.30503 | ||
| 245 | 0 | 0 | |a Electrical Conductances of Tetrabutylammonium Bromide, Sodium Tetraphenylborate and Sodium Bromide in 2-Ethoxyethanol in the Temperature Range 35-50°C |h [Elektronische Daten] |c [Purushottam Haldar, Bijan Das] |
| 520 | 3 | |a The electrical conductances of the solutions of tetrabutylammonium bromide (Bu4NBr), sodium tetraphenylborate (NaPh4B) and sodium bromide (NaBr) in 2-ethoxyethanol have been reported at 35, 40, 45 and 50°C. The conductance data have been analyzed by the 1978 Fuoss conductance-concentration equation in terms of the limiting molar conductance (Λ0), the association constant (KΛ) and the association diameter (R). The ionic contributions to the limiting molar conductances (Λ0) have been estimated using the "reference electrolyte” tetrabutylammonium tetraphenylborate (Bu4NPh4B). Appreciable ionic association was observed for all of these electrolytes which were found to exist in the form of solvent-separated ion-pairs in 2-ethoxyethanol. The tetrabutylammonium and tetraphenylborate ions are found to remain scarcely solvated whereas the sodium and bromide ions undergo substantial solvation in 2-ethoxyethanol medium in the temperature range investigated here. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Haldar |D Purushottam |4 aut | |
| 700 | 1 | |a Das |D Bijan |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/5/2004(2004-05-01), 599-610 |x 0942-9352 |q 218:5/2004<599 |1 2004 |2 218 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.218.5.599.30503 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.218.5.599.30503 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Haldar |D Purushottam |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Das |D Bijan |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/5/2004(2004-05-01), 599-610 |x 0942-9352 |q 218:5/2004<599 |1 2004 |2 218 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||