Ultratrace and isotope ratios analyses of some radionuclides by ICP-MS

Verfasser / Beitragende:
[A. I. Helal, N. F. Zahran, M. A. Amr, A. M. Abd El-Lateef, I. I. Bashter, H. T. Mohsen, Y. Abbas]
Ort, Verlag, Jahr:
2004
Enthalten in:
Radiochimica Acta/International journal for chemical aspects of nuclear science and technology, 92/4-6/2004(2004-04-01), 369-374
Format:
Artikel (online)
ID: 378907220
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024 7 0 |a 10.1524/ract.92.4.369.35580  |2 doi 
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245 0 0 |a Ultratrace and isotope ratios analyses of some radionuclides by ICP-MS  |h [Elektronische Daten]  |c [A. I. Helal, N. F. Zahran, M. A. Amr, A. M. Abd El-Lateef, I. I. Bashter, H. T. Mohsen, Y. Abbas] 
520 3 |a Extensive work is under way using High Resolution-ICP-MS for 90Sr, 234U, 235U, 238U, 239Pu, 240Pu, and 241Am detection. Sample preparation procedures based on liquid-liquid extraction and ion exchange chromatography were developed. Sr, U, Pu, and Am were separated from their matrix and concentrated to improve the power of detection in the mass spectrometer. A microconcentric nebulizer with a desolvation introduction system (Ardius) is used. Instrumental limits of detection using Sr and U standard solutions are 0.01ppt and 0.006ppt for Sr and U, respectively. A study is presented on the mass interferences for the specified radionuclides. In the environmental samples investigated the 90Sr/86Sr isotope ratio is 6.02×10-9 and for 240Pu/239Pu the isotope ratio is 0.17. 
540 |a © 2004 Oldenbourg Wissenschaftsverlag GmbH 
690 7 |a Laboratory techniques, experiments  |2 nationallicence 
690 7 |a Analytical chemistry  |2 nationallicence 
690 7 |a Inorganic chemistry  |2 nationallicence 
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700 1 |a Zahran  |D N. F.  |4 aut 
700 1 |a Amr  |D M. A.  |4 aut 
700 1 |a Abd El-Lateef  |D A. M.  |4 aut 
700 1 |a Bashter  |D I. I.  |4 aut 
700 1 |a Mohsen  |D H. T.  |4 aut 
700 1 |a Abbas  |D Y.  |4 aut 
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