Reaction of O(3P) Atoms with Benzene
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| 024 | 7 | 0 | |a 10.1524/zpch.218.4.391.29202 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.218.4.391.29202 | ||
| 245 | 0 | 0 | |a Reaction of O(3P) Atoms with Benzene |h [Elektronische Daten] |c [Torsten Berndt, Olaf Böge] |
| 520 | 3 | |a The gas-phase reaction of O(3P) atoms with benzene was investigated in a flow system in the pressure range of 50-100mbar and a temperature of 295 ± 2K with a focus on the product formation. O2 concentrations in the carrier gas were in the range of (7.7-84) × 1014 molecule cm−3. The primary stable products detected were phenol, benzene oxide/oxepin and a not identified compound with the probable composition C5H6O. The yields of phenol and benzene oxide/oxepin were 0.12 ± 0.02 and 0.26 ± 0.06, respectively, being not affected by the experimental conditions. For benzene oxide/oxepin, a rapid consecutive reaction with O(3P) atoms was observed with a rate coefficient of k(295K) = (1.1 ± 0.1) × 10−10cm3 molecule−1s−1 measured at a pressure of 100mbar. A substance with the formula C6H6O2 (likely oxepin 4,5-epoxide or oxepin 2,3-epoxide), the isomers of muconaldehyde, as well as formic acid, acrolein and trans-butenedial were identified as products of the reaction of O(3P) atoms with benzene oxide/oxepin. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Berndt |D Torsten |4 aut | |
| 700 | 1 | |a Böge |D Olaf |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/4/2004(2004-04-01), 391-404 |x 0942-9352 |q 218:4/2004<391 |1 2004 |2 218 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.218.4.391.29202 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.218.4.391.29202 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Berndt |D Torsten |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Böge |D Olaf |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/4/2004(2004-04-01), 391-404 |x 0942-9352 |q 218:4/2004<391 |1 2004 |2 218 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||