Solid state miscibility in the pseudo-binary TiO2—(FeSb)O4 system at 1373 K
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| 024 | 7 | 0 | |a 10.1524/zkri.219.8.487.38327 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.8.487.38327 | ||
| 245 | 0 | 0 | |a Solid state miscibility in the pseudo-binary TiO2—(FeSb)O4 system at 1373 K |h [Elektronische Daten] |c [Alberto Martinelli, Maurizio Ferretti, Riccardo Basso, Roberto Cabella, Gabriella Lucchetti, Pietro Marescotti, Vincenzo Buscaglia] |
| 520 | 3 | |a The tetragonal rutile-type (FeSb)O4 compound was synthesized reacting Fe2O3 and Sb2O3 in O2. Solid solubility in the pseudo-binary TiO2—(FeSb)O4 (rutile — tripuhyite) system was investigated annealing powder mixtures characterized by different TiO2/(FeSb)O4 molar ratios in an O2 flux. Complete miscibility was found in the whole compositional range at 1373 K. The crystal structures of (FeSb)O4 and selected terms of the (Ti2xFe1-xSb1-x)O4 solid solution (0 ≤ x ≤ 1) were refined from X-ray powder diffraction data using the Rietveld method. Selective broadening of the X-ray lines was observed and analyzed by means of the Gaussian quadratic plot. Line broadening is probably related to a phase transformation taking place at low temperature, as suggested by the excess molar volume of the solid solution. As a result local chemical inhomogeneity and microstrain in the direction perpendicular to the 00l lattice planes for compositions 0.2 ≤ x ≤ 0.6 are generated. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Martinelli |D Alberto |4 aut | |
| 700 | 1 | |a Ferretti |D Maurizio |4 aut | |
| 700 | 1 | |a Basso |D Riccardo |4 aut | |
| 700 | 1 | |a Cabella |D Roberto |4 aut | |
| 700 | 1 | |a Lucchetti |D Gabriella |4 aut | |
| 700 | 1 | |a Marescotti |D Pietro |4 aut | |
| 700 | 1 | |a Buscaglia |D Vincenzo |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/8(2004-08-01), 487-493 |x 2194-4946 |q 219:8<487 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.8.487.38327 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.8.487.38327 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Martinelli |D Alberto |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ferretti |D Maurizio |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Basso |D Riccardo |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Cabella |D Roberto |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Lucchetti |D Gabriella |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Marescotti |D Pietro |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Buscaglia |D Vincenzo |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/8(2004-08-01), 487-493 |x 2194-4946 |q 219:8<487 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||