caa a22 4500 378921681 CHVBK 20180305123607.0 cr unu---uuuuu 161128e20040101xx s 000 0 eng 10.1351/pac200476071345 doi (NATIONALLICENCE)gruyter-10.1351/pac200476071345 Controlling the assembly of hydrogen-bonded supramolecular polymers by the strategy of molecular tectonics [Elektronische Daten] [M.-Č. Perron, F. Monchamp, Hugues Duval, Danielle Boils-Boissier, J. D. Wuest] Studies of how hydrogen bonding can be used to control molecular association continue to yield exciting discoveries in supramolecular chemistry. A simple way to make molecules that associate predictably is to link carefully selected cores to functional groups that form multiple hydrogen bonds according to reliable patterns. Bifunctional molecules constructed according to this strategy can associate to form linear aggregates robust enough to warrant the name supramolecular polymers, even though the bifunctional monomers are joined only by hydrogen bonds. More complex molecules with multiple hydrogen-bonding sites can be devised so that neighbors are held in predetermined positions, giving crystalline solids with predictable architectures and properties not previously seen in other materials. Initial studies of the ability of such compounds to associate in solution and in the molten state suggest that hydrogen-bonded networks can be purposefully designed to create novel par- tially ordered liquid materials, including liquid crystals, gels, and fluids with unusual rheological properties. © 2013 Walter de Gruyter GmbH, Berlin/Boston Perron M.-Č Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut Monchamp F. Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut Duval Hugues Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut Boils-Boissier Danielle Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut Wuest J. D. Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut Pure and Applied Chemistry De Gruyter 76/7-8(2004-01-01), 1345-1351 0033-4545 76:7-8<1345 2004 76 pac https://doi.org/10.1351/pac200476071345 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200476071345 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Perron M.-Č Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut NATIONALLICENCE 700 1- Monchamp F. Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut NATIONALLICENCE 700 1- Duval Hugues Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut NATIONALLICENCE 700 1- Boils-Boissier Danielle Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut NATIONALLICENCE 700 1- Wuest J. D. Département de Chimie, Université de Montréal, Montréal, Québec H3C 3J7, Canada; Xerox Research Centre of Canada, 2660 Speakman Drive, Mississauga, Ontario L5K 2L1, Canada aut NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 76/7-8(2004-01-01), 1345-1351 0033-4545 76:7-8<1345 2004 76 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter