Composite tectocapsules via the self-assembly of functionalized poly(divinylbenzene) microspheres

Verfasser / Beitragende:
[L. M. Croll, H. D. H. Stöver]
Ort, Verlag, Jahr:
2004
Enthalten in:
Pure and Applied Chemistry, 76/7-8(2004-01-01), 1365-1374
Format:
Artikel (online)
ID: 378921711
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024 7 0 |a 10.1351/pac200476071365  |2 doi 
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245 0 0 |a Composite tectocapsules via the self-assembly of functionalized poly(divinylbenzene) microspheres  |h [Elektronische Daten]  |c [L. M. Croll, H. D. H. Stöver] 
520 3 |a Poly(divinylbenzene-55)[poly(DVB-55] microspheres were used as building blocks to form polymer capsule walls consisting of interconnected microspheres. The microspheres had to be surface-functionalized with maleic acid to facilitate their interfacial assembly. In addition, porous and functionalized poly(DVB-55) microspheres were embedded across interfacial polyurea capsule membranes to form composite tectocapsules where release of core materials is designed to occur through the microsphere pores, rather than by conventional wall diffusion. Electron microscopy and X-ray spectromicroscopy were used to characterize the wall compositions, and release data are presented to illustrate the role of microspheres acting as release portals. 
540 |a © 2013 Walter de Gruyter GmbH, Berlin/Boston 
700 1 |a Croll  |D L. M.  |u Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada  |4 aut 
700 1 |a Stöver  |D H. D. H.  |u Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Croll  |D L. M.  |u Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Stöver  |D H. D. H.  |u Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada  |4 aut 
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