Substrate scope in the olefin cyclopropanation reaction catalyzed by m-oxo-bis[(salen)iron(III)] complexes
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| 024 | 7 | 0 | |a 10.1351/pac200476030645 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1351/pac200476030645 | ||
| 245 | 0 | 0 | |a Substrate scope in the olefin cyclopropanation reaction catalyzed by m-oxo-bis[(salen)iron(III)] complexes |h [Elektronische Daten] |c [S. K. Edulji, S. T. Nguyen] |
| 520 | 3 | |a The cyclopropanation of various alkenes with different diazoester compounds was investigated using two different μ-oxo-bis[(salen)iron(III)] complexes, [Fe(3,3',5,5'-tBu4salen)]2O and [Fe(salen)]2O. Ethyl diazoacetate (EDA), tert-butyl diazoacetate (tBDA), and ethyl diazoacetoacetate (EDAA) were used with mono- and disubstituted terminal olefins (styrene and 1,1-diphenyl ethylene, respectively), internal olefin (trans-β-methyl styrene), and an electron-rich alkene (n-butyl vinyl ether). Moderate-to-good cyclopropanation yields were obtained for most substrates. | |
| 540 | |a © 2013 Walter de Gruyter GmbH, Berlin/Boston | ||
| 700 | 1 | |a Edulji |D S. K. |u Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA |4 aut | |
| 700 | 1 | |a Nguyen |D S. T. |u Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA |4 aut | |
| 773 | 0 | |t Pure and Applied Chemistry |d De Gruyter |g 76/3(2004-01-01), 645-649 |x 0033-4545 |q 76:3<645 |1 2004 |2 76 |o pac | |
| 856 | 4 | 0 | |u https://doi.org/10.1351/pac200476030645 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1351/pac200476030645 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Edulji |D S. K. |u Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Nguyen |D S. T. |u Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Pure and Applied Chemistry |d De Gruyter |g 76/3(2004-01-01), 645-649 |x 0033-4545 |q 76:3<645 |1 2004 |2 76 |o pac | ||
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| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||