Negative nonlinear effect in aquo palladium catalysis depending on tropos biphenylphosphine ligand chirality controlled by chiral diaminobinaphthyl activator

Verfasser / Beitragende:
[K. Mikami, Kohsuke Aikawa, Masahiro Yamanaka]
Ort, Verlag, Jahr:
2004
Enthalten in:
Pure and Applied Chemistry, 76/3(2004-01-01), 537-540
Format:
Artikel (online)
ID: 378923064
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245 0 0 |a Negative nonlinear effect in aquo palladium catalysis depending on tropos biphenylphosphine ligand chirality controlled by chiral diaminobinaphthyl activator  |h [Elektronische Daten]  |c [K. Mikami, Kohsuke Aikawa, Masahiro Yamanaka] 
520 3 |a Asymmetric activation of aquo Pd catalysts with tropos biphenylphosphine (BIPHEP) ligands by a chiral diaminobinaphtyl (DABN) activator exhibits a remarkable negative nonlinear effect, (-)-NLE, with higher catalytic efficiency than that achieved by enantiopure atropos BINAP- or tropos BIPHEP-Pd catalysts without DABN activator. 
540 |a © 2013 Walter de Gruyter GmbH, Berlin/Boston 
700 1 |a Mikami  |D K.  |u Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan  |4 aut 
700 1 |a Aikawa  |D Kohsuke  |u Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan  |4 aut 
700 1 |a Yamanaka  |D Masahiro  |u Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Aikawa  |D Kohsuke  |u Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Yamanaka  |D Masahiro  |u Department of Applied Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan  |4 aut 
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