New methods for the synthesis of heterocyclic compounds

Verfasser / Beitragende:
[Aldo Caiazzo, Shadi Dalili, C. Picard, M. Sasaki, T. Siu, A. K. Yudin]
Ort, Verlag, Jahr:
2004
Enthalten in:
Pure and Applied Chemistry, 76/3(2004-01-01), 603-613
Format:
Artikel (online)
ID: 378923080
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245 0 0 |a New methods for the synthesis of heterocyclic compounds  |h [Elektronische Daten]  |c [Aldo Caiazzo, Shadi Dalili, C. Picard, M. Sasaki, T. Siu, A. K. Yudin] 
520 3 |a Due to frequent occurrence of nitrogen-containing groups among the biologically active compounds, chemoselective functionalization of organic molecules with nitrogen-containing functional groups is an important area of organic synthesis. We have proposed and implemented a new strategy toward design of nitrogen-transfer reactions on inert electrode surfaces with a particular focus on the generation and trapping of highly reactive nitrogen-transfer agents. A wide range of structurally dissimilar olefins can be readily transformed into the corresponding aziridines. The resulting aziridines are precursors to a range of catalysts via nucleophilic ring-opening with diaryl- and dialkyl phosphines. Another strategy explored in the context of oxidative nitrogen transfer is cycloamination of olefins using NH aziridines. 
540 |a © 2013 Walter de Gruyter GmbH, Berlin/Boston 
700 1 |a Caiazzo  |D Aldo  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
700 1 |a Dalili  |D Shadi  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
700 1 |a Picard  |D C.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
700 1 |a Sasaki  |D M.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
700 1 |a Siu  |D T.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
700 1 |a Yudin  |D A. K.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Dalili  |D Shadi  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Picard  |D C.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Sasaki  |D M.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Siu  |D T.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Yudin  |D A. K.  |u Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada; Ylektra, Inc., 100 University Ave., 10th Floor, South Tower, Toronto, Ontario M5J 1V6, Canada  |4 aut 
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