Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes
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| 008 | 161128e20040101xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1351/pac200476030557 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1351/pac200476030557 | ||
| 245 | 0 | 0 | |a Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes |h [Elektronische Daten] |c [Y. D. Y. L. Getzler, Viswanath Mahadevan, E. B. Lobkovsky, G. W. Coates] |
| 520 | 3 | |a The stereochemistry of epoxide carbonylation using bimetallic [Lewis acid]+[Co(CO)4]- complexes is reported. The achiral complex [(salph)Al(THF)2][Co(CO)4] stereospecifically carbonylates cis- and trans-2-butene oxide to the trans- and cis-β-lactones, respectively. Preliminary experiments regarding the carbonylative kinetic resolution of racemic trans-2-butene oxide using the enantiomerically pure complex [(R,R-salcy)Al(THF)2][Co(CO)4] are also reported. | |
| 540 | |a © 2013 Walter de Gruyter GmbH, Berlin/Boston | ||
| 700 | 1 | |a Getzler |D Y. D. Y. L. |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | |
| 700 | 1 | |a Mahadevan |D Viswanath |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | |
| 700 | 1 | |a Lobkovsky |D E. B. |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | |
| 700 | 1 | |a Coates |D G. W. |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | |
| 773 | 0 | |t Pure and Applied Chemistry |d De Gruyter |g 76/3(2004-01-01), 557-564 |x 0033-4545 |q 76:3<557 |1 2004 |2 76 |o pac | |
| 856 | 4 | 0 | |u https://doi.org/10.1351/pac200476030557 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1351/pac200476030557 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Getzler |D Y. D. Y. L. |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Mahadevan |D Viswanath |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Lobkovsky |D E. B. |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Coates |D G. W. |u Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Pure and Applied Chemistry |d De Gruyter |g 76/3(2004-01-01), 557-564 |x 0033-4545 |q 76:3<557 |1 2004 |2 76 |o pac | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||