caa a22 4500 378923137 CHVBK 20180305123610.0 cr unu---uuuuu 161128e20040101xx s 000 0 eng 10.1351/pac200476030557 doi (NATIONALLICENCE)gruyter-10.1351/pac200476030557 Stereochemistry of epoxide carbonylation using bimetallic Lewis acid/metal carbonyl complexes [Elektronische Daten] [Y. D. Y. L. Getzler, Viswanath Mahadevan, E. B. Lobkovsky, G. W. Coates] The stereochemistry of epoxide carbonylation using bimetallic [Lewis acid]+[Co(CO)4]- complexes is reported. The achiral complex [(salph)Al(THF)2][Co(CO)4] stereospecifically carbonylates cis- and trans-2-butene oxide to the trans- and cis-β-lactones, respectively. Preliminary experiments regarding the carbonylative kinetic resolution of racemic trans-2-butene oxide using the enantiomerically pure complex [(R,R-salcy)Al(THF)2][Co(CO)4] are also reported. © 2013 Walter de Gruyter GmbH, Berlin/Boston Getzler Y. D. Y. L. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut Mahadevan Viswanath Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut Lobkovsky E. B. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut Coates G. W. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut Pure and Applied Chemistry De Gruyter 76/3(2004-01-01), 557-564 0033-4545 76:3<557 2004 76 pac https://doi.org/10.1351/pac200476030557 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200476030557 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Getzler Y. D. Y. L. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut NATIONALLICENCE 700 1- Mahadevan Viswanath Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut NATIONALLICENCE 700 1- Lobkovsky E. B. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut NATIONALLICENCE 700 1- Coates G. W. Baker Laboratory, Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853-1301, USA aut NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 76/3(2004-01-01), 557-564 0033-4545 76:3<557 2004 76 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter