caa a22 4500 378923196 CHVBK 20180305123610.0 cr unu---uuuuu 161128e20040101xx s 000 0 eng 10.1351/pac200476030507 doi (NATIONALLICENCE)gruyter-10.1351/pac200476030507 Hartwig J. F. Department of Chemistry, Yale University, P.O.Box 208107, New Haven, CT 06520-8107, USA Development of catalysts for the hydroamination of olefins [Elektronische Daten] [J. F. Hartwig] Studies on the development of palladium, nickel, and rhodium catalysts for the hydroamination of dienes and vinylarenes are described. Enantioselective catalysts based on palladium have been developed for the addition of arylamines to dienes and for Markovnikov addition of arylamines to vinylarenes. In addition, nickel catalysts for the addition of aliphatic amines to dienes have been developed, and rhodium catalysts for the first transition metal-catalyzed aminations of vinylarenes that generate terminal amines as the major product are described. Mechanistic data on the hydroamination of vinylarenes with palladium and rhodium is also provided. © 2013 Walter de Gruyter GmbH, Berlin/Boston Pure and Applied Chemistry De Gruyter 76/3(2004-01-01), 507-516 0033-4545 76:3<507 2004 76 pac https://doi.org/10.1351/pac200476030507 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200476030507 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Hartwig J. F. Department of Chemistry, Yale University, P.O.Box 208107, New Haven, CT 06520-8107, USA NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 76/3(2004-01-01), 507-516 0033-4545 76:3<507 2004 76 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter