Recent advances in transition metal-catalyzed or -mediated cyclization of 2,3-allenoic acids: New methodologies for the synthesis of butenolides

Verfasser / Beitragende:
[S. Ma]
Ort, Verlag, Jahr:
2004
Enthalten in:
Pure and Applied Chemistry, 76/3(2004-01-01), 651-656
Format:
Artikel (online)
ID: 378923218
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024 7 0 |a 10.1351/pac200476030651  |2 doi 
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100 1 |a Ma  |D S.  |u State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China 
245 1 0 |a Recent advances in transition metal-catalyzed or -mediated cyclization of 2,3-allenoic acids: New methodologies for the synthesis of butenolides  |h [Elektronische Daten]  |c [S. Ma] 
520 3 |a The cyclization reactions of 2,3-allenoic acids or their salts with optically active bases affording butenolides are discussed. Two reaction pathways were observed: (1) intermolecular carbometallation-intramolecular allylation; (2) cyclic oxymetallation-reductive elimination. High efficiency of chirality transfer was realized with the latter case. 
540 |a © 2013 Walter de Gruyter GmbH, Berlin/Boston 
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