Synthesis, spectroscopy, thermal behaviour and molecular structure of orotatotriethanolaminecopper(II) monohydrate
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| 024 | 7 | 0 | |a 10.1524/zkri.219.5.300.32749 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.5.300.32749 | ||
| 245 | 0 | 0 | |a Synthesis, spectroscopy, thermal behaviour and molecular structure of orotatotriethanolaminecopper(II) monohydrate |h [Elektronische Daten] |c [Halis Ölmez, Hasan İçbudak, Okan Zafer Yeşilel, Cengiz Arıcı, Dinçer Ülkü] |
| 520 | 3 | |a The orotatotriethanolaminecopper(II) monohydrate, [Cu(C5H2N2O4)(C6H15NO3)] · H2O, has been synthesized and characterized with physico-chemical methods (IR and UV-Vis spectroscopy, magnetic susceptibility, conductivity and thermoanalytical measurements) and X-ray diffraction. The structure derived from physico-chemical methods is consistent with that of the X-ray diffraction. The compound crystallizes in the monoclinic system, space group P21/n, with a = 8.6282(12), b = 16.9919(18), c = 10.6985(15) Å, β = 110.08(3)°, V = 1473.1(3) Å3, Z = 4. The copper atom is chelated by the deprotonated nitrogen pyrimidine atom and by the carboxylate oxygen atom of the orotate dianion ligand, and by the nitrogen and oxygen atoms of the triethanolamine ligand. The title compound has a distorted octahedral coordination geometry. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Ölmez |D Halis |4 aut | |
| 700 | 1 | |a İçbudak |D Hasan |4 aut | |
| 700 | 1 | |a Yeşilel |D Okan Zafer |4 aut | |
| 700 | 1 | |a Arıcı |D Cengiz |4 aut | |
| 700 | 1 | |a Ülkü |D Dinçer |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/5(2004-05-01), 300-304 |x 2194-4946 |q 219:5<300 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.5.300.32749 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.5.300.32749 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ölmez |D Halis |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a İçbudak |D Hasan |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yeşilel |D Okan Zafer |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Arıcı |D Cengiz |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ülkü |D Dinçer |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/5(2004-05-01), 300-304 |x 2194-4946 |q 219:5<300 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||