caa a22 4500 378923390 CHVBK 20180305123611.0 cr unu---uuuuu 161128e20040501xx s 000 0 eng 10.1524/zkri.219.5.300.32749 doi (NATIONALLICENCE)gruyter-10.1524/zkri.219.5.300.32749 Synthesis, spectroscopy, thermal behaviour and molecular structure of orotatotriethanolaminecopper(II) monohydrate [Elektronische Daten] [Halis Ölmez, Hasan İçbudak, Okan Zafer Yeşilel, Cengiz Arıcı, Dinçer Ülkü] The orotatotriethanolaminecopper(II) monohydrate, [Cu(C5H2N2O4)(C6H15NO3)] · H2O, has been synthesized and characterized with physico-chemical methods (IR and UV-Vis spectroscopy, magnetic susceptibility, conductivity and thermoanalytical measurements) and X-ray diffraction. The structure derived from physico-chemical methods is consistent with that of the X-ray diffraction. The compound crystallizes in the monoclinic system, space group P21/n, with a = 8.6282(12), b = 16.9919(18), c = 10.6985(15) Å, β = 110.08(3)°, V = 1473.1(3) Å3, Z = 4. The copper atom is chelated by the deprotonated nitrogen pyrimidine atom and by the carboxylate oxygen atom of the orotate dianion ligand, and by the nitrogen and oxygen atoms of the triethanolamine ligand. The title compound has a distorted octahedral coordination geometry. © 2004 Oldenbourg Wissenschaftsverlag GmbH Crystallography nationallicence Inorganic chemistry nationallicence Organic chemistry nationallicence Ölmez Halis aut İçbudak Hasan aut Yeşilel Okan Zafer aut Arıcı Cengiz aut Ülkü Dinçer aut Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 219/5(2004-05-01), 300-304 2194-4946 219:5<300 2004 219 zkri https://doi.org/10.1524/zkri.219.5.300.32749 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zkri.219.5.300.32749 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ölmez Halis aut NATIONALLICENCE 700 1- İçbudak Hasan aut NATIONALLICENCE 700 1- Yeşilel Okan Zafer aut NATIONALLICENCE 700 1- Arıcı Cengiz aut NATIONALLICENCE 700 1- Ülkü Dinçer aut NATIONALLICENCE 773 0- Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 219/5(2004-05-01), 300-304 2194-4946 219:5<300 2004 219 zkri CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter