Crystal structure determination of Ga3(H3O)H8(PO4)6 · 6 H2O from X-ray powder diffraction data
| LEADER | caa a22 4500 | ||
|---|---|---|---|
| 001 | 378923412 | ||
| 003 | CHVBK | ||
| 005 | 20180305123611.0 | ||
| 007 | cr unu---uuuuu | ||
| 008 | 161128e20040501xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1524/zkri.219.5.267.32747 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.5.267.32747 | ||
| 245 | 0 | 0 | |a Crystal structure determination of Ga3(H3O)H8(PO4)6 · 6 H2O from X-ray powder diffraction data |h [Elektronische Daten] |c [Ludmila S. Ivashkevich, Alexander S. Lyakhov, Anatoly F. Selevich, Anatoly I. Lesnikovich] |
| 520 | 3 | |a The crystal structure of the gallium hydrogen phosphate hydrate, Ga3(H3O)H8(PO4)6 · 6 H2O, has been determined from X-ray powder diffraction data. The structure is trigonal, space group P31c (No. 159), with unit cell dimensions a = 9.0227(1) Å, c = 16.6389(3) Å, V = 1173.08(3) Å3, Z = 2, and Dx = 2.59 g/cm3. The structure was solved by direct methods using EXPO program and refined by FULLPROF package to RBragg value of 8.6%. Positions of hydrogen atoms were not defined. There are three unique gallium atoms in the crystal structure, having octahedral oxygen coordination. GaO6 octahedra are linked together via the corners of PO4 tetrahedra to form a three-dimensional network with channels running along the c axis. There are two types of water molecules in the crystal, which essentially differ in their atomic environment. Oxonium cations, lying on crystallographic threefold axis, are surrounded by oxygen atoms of the phosphate groups and water molecules. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Ivashkevich |D Ludmila S. |4 aut | |
| 700 | 1 | |a Lyakhov |D Alexander S. |4 aut | |
| 700 | 1 | |a Selevich |D Anatoly F. |4 aut | |
| 700 | 1 | |a Lesnikovich |D Anatoly I. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/5(2004-05-01), 267-271 |x 2194-4946 |q 219:5<267 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.5.267.32747 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.5.267.32747 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ivashkevich |D Ludmila S. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Lyakhov |D Alexander S. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Selevich |D Anatoly F. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Lesnikovich |D Anatoly I. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/5(2004-05-01), 267-271 |x 2194-4946 |q 219:5<267 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||