Synthesis and crystal structure of two dimeric cadmium(II) complexes bonded with pseudohalides, 1.1 and 1.3 bonding
| LEADER | caa a22 4500 | ||
|---|---|---|---|
| 001 | 378923447 | ||
| 003 | CHVBK | ||
| 005 | 20180305123611.0 | ||
| 007 | cr unu---uuuuu | ||
| 008 | 161128e20040501xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1524/zkri.219.5.295.32745 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.5.295.32745 | ||
| 245 | 0 | 0 | |a Synthesis and crystal structure of two dimeric cadmium(II) complexes bonded with pseudohalides, 1.1 and 1.3 bonding |h [Elektronische Daten] |c [Filiz Ercan, Cengiz Arıcı, Dinçer Ülkü, Raif Kurtaran, Mecit Aksu, Orhan Atakol] |
| 520 | 3 | |a Two different complexes were obtained from (dmpp) and Cd(II) ions with the aid of pseudohalide ions in non-aqueous solvents. The dinuclear complex formed with thiocyanate ions show, using XRD, to posses two 1.3 bond μ bridges [CdL(SCN)2]2. The other dinuclear complex was also seen to form with cyanate ions but with the μ-bridge in a 1.1 position [CdL(OCN)2]. All Cd atoms are located in a distorted octahedral environment in 1 and 2 complexes. The Cd Cda distances are 6.032(4) Å in 1 and 3.704(3) Å in 2, respectively. The N—C—S and O—C—N angles are approximately linear as 178.1(3) and 178.6(3)° in 1 and 177.2(5) and 176.9(7)° in 2, respectively. The Cd—(μN,S-NCS)2—Cda bonds form a zig-zag structure in 1 and the Cd—(μO,N-OCN)2—Cda bonds form a distorted square planar in 2. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Ercan |D Filiz |4 aut | |
| 700 | 1 | |a Arıcı |D Cengiz |4 aut | |
| 700 | 1 | |a Ülkü |D Dinçer |4 aut | |
| 700 | 1 | |a Kurtaran |D Raif |4 aut | |
| 700 | 1 | |a Aksu |D Mecit |4 aut | |
| 700 | 1 | |a Atakol |D Orhan |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/5(2004-05-01), 295-299 |x 2194-4946 |q 219:5<295 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.5.295.32745 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.5.295.32745 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ercan |D Filiz |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Arıcı |D Cengiz |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Ülkü |D Dinçer |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Kurtaran |D Raif |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Aksu |D Mecit |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Atakol |D Orhan |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/5(2004-05-01), 295-299 |x 2194-4946 |q 219:5<295 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||