caa a22 4500 378923447 CHVBK 20180305123611.0 cr unu---uuuuu 161128e20040501xx s 000 0 eng 10.1524/zkri.219.5.295.32745 doi (NATIONALLICENCE)gruyter-10.1524/zkri.219.5.295.32745 Synthesis and crystal structure of two dimeric cadmium(II) complexes bonded with pseudohalides, 1.1 and 1.3 bonding [Elektronische Daten] [Filiz Ercan, Cengiz Arıcı, Dinçer Ülkü, Raif Kurtaran, Mecit Aksu, Orhan Atakol] Two different complexes were obtained from (dmpp) and Cd(II) ions with the aid of pseudohalide ions in non-aqueous solvents. The dinuclear complex formed with thiocyanate ions show, using XRD, to posses two 1.3 bond μ bridges [CdL(SCN)2]2. The other dinuclear complex was also seen to form with cyanate ions but with the μ-bridge in a 1.1 position [CdL(OCN)2]. All Cd atoms are located in a distorted octahedral environment in 1 and 2 complexes. The Cd Cda distances are 6.032(4) Å in 1 and 3.704(3) Å in 2, respectively. The N—C—S and O—C—N angles are approximately linear as 178.1(3) and 178.6(3)° in 1 and 177.2(5) and 176.9(7)° in 2, respectively. The Cd—(μN,S-NCS)2—Cda bonds form a zig-zag structure in 1 and the Cd—(μO,N-OCN)2—Cda bonds form a distorted square planar in 2. © 2004 Oldenbourg Wissenschaftsverlag GmbH Crystallography nationallicence Inorganic chemistry nationallicence Organic chemistry nationallicence Ercan Filiz aut Arıcı Cengiz aut Ülkü Dinçer aut Kurtaran Raif aut Aksu Mecit aut Atakol Orhan aut Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 219/5(2004-05-01), 295-299 2194-4946 219:5<295 2004 219 zkri https://doi.org/10.1524/zkri.219.5.295.32745 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zkri.219.5.295.32745 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Ercan Filiz aut NATIONALLICENCE 700 1- Arıcı Cengiz aut NATIONALLICENCE 700 1- Ülkü Dinçer aut NATIONALLICENCE 700 1- Kurtaran Raif aut NATIONALLICENCE 700 1- Aksu Mecit aut NATIONALLICENCE 700 1- Atakol Orhan aut NATIONALLICENCE 773 0- Zeitschrift für Kristallographie - Crystalline Materials De Gruyter Oldenbourg 219/5(2004-05-01), 295-299 2194-4946 219:5<295 2004 219 zkri CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter