caa a22 4500 378924834 CHVBK 20180305123614.0 cr unu---uuuuu 161128e20040601xx s 000 0 eng 10.1524/zpch.218.6.679.33455 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.6.679.33455 Single Ionic Volumes in Acetonitrile-Organic Cosolvent Mixtures at 298.15K [Elektronische Daten] [Henryk Piekarski, Alina Piekarska, Kinga Kubalczyk] Densities of binary nonaqueous mixtures of acetonitrile (AN) with 2-methoxyethanol (ME), N,N-dimethylacetamide (DMA) and propylene carbonate (PC) were determined over the whole composition range at 298.15K. The excess molar volumes and the partial molar volumes of both components were calculated from these data. Densities of solutions of NaI, NaBPh4 and Ph4PI in solvent mixtures AN+ME and AN+DMA and of NaI solutions in mixtures of AN+PC were measured over the whole composition range of the mixed solvents at an electrolyte concentration equal 0.05moldm−3. From these densities, apparent molar volumes of electrolytes and ions were evaluated and analyzed. The relationship between the apparent molar volumes of ions and (κT/ε) parameter was tested and discussed. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Piekarski Henryk aut Piekarska Alina aut Kubalczyk Kinga aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/6/2004(2004-06-01), 679-698 0942-9352 218:6/2004<679 2004 218 zpch https://doi.org/10.1524/zpch.218.6.679.33455 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.6.679.33455 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Piekarski Henryk aut NATIONALLICENCE 700 1- Piekarska Alina aut NATIONALLICENCE 700 1- Kubalczyk Kinga aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/6/2004(2004-06-01), 679-698 0942-9352 218:6/2004<679 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter