Coupled transport/reaction modelling of copper canister corrosion aided by microbial processes

Verfasser / Beitragende:
[Jinsong Liu, Ivars Neretnieks]
Ort, Verlag, Jahr:
2004
Enthalten in:
Radiochimica Acta/International journal for chemical aspects of nuclear science and technology, 92/9-11/2004(2004-11-01), 849-854
Format:
Artikel (online)
ID: 378927248
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024 7 0 |a 10.1524/ract.92.9.849.54994  |2 doi 
035 |a (NATIONALLICENCE)gruyter-10.1524/ract.92.9.849.54994 
245 0 0 |a Coupled transport/reaction modelling of copper canister corrosion aided by microbial processes  |h [Elektronische Daten]  |c [Jinsong Liu, Ivars Neretnieks] 
520 3 |a Copper canister corrosion is an important issue in the concept of a nuclear fuel repository. Previous studies indicate that the oxygen-free copper canister could hold its integrity for more than 100000years in the repository environment. Microbial processes may reduce sulphate to sulphide and considerably increase the amount of sulphide available for corrosion. In this paper, a coupled transport/reaction model is developed to account for the transport of chemical species produced by microbial processes. The corroding agents like sulphide would come not only from the intruding groundwater, but also from the reduction of sulphate near the canister. The reaction of sulphate-reducing bacteria and the transport of sulphide in the bentonite buffer is included in the model. The local depth of copper canister corrosion is calculated by the model. 
540 |a © 2004 Oldenbourg Wissenschaftsverlag GmbH 
690 7 |a Laboratory techniques, experiments  |2 nationallicence 
690 7 |a Analytical chemistry  |2 nationallicence 
690 7 |a Inorganic chemistry  |2 nationallicence 
700 1 |a Liu  |D Jinsong  |4 aut 
700 1 |a Neretnieks  |D Ivars  |4 aut 
773 0 |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 92/9-11/2004(2004-11-01), 849-854  |x 0033-8230  |q 92:9-11/2004<849  |1 2004  |2 92  |o ract 
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950 |B NATIONALLICENCE  |P 700  |E 1-  |a Liu  |D Jinsong  |4 aut 
950 |B NATIONALLICENCE  |P 700  |E 1-  |a Neretnieks  |D Ivars  |4 aut 
950 |B NATIONALLICENCE  |P 773  |E 0-  |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology  |d Oldenbourg Wissenschaftsverlag GmbH  |g 92/9-11/2004(2004-11-01), 849-854  |x 0033-8230  |q 92:9-11/2004<849  |1 2004  |2 92  |o ract 
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