Guidelines for calibration in analytical chemistry. Part 2: Multicomponent calibration (IUPAC Technical Report)

Verfasser / Beitragende:
[Klaus Danzer, M. Otto, L. A. Currie]
Ort, Verlag, Jahr:
2004
Enthalten in:
Pure and Applied Chemistry, 76/6(2004-01-01), 1215-1225
Format:
Artikel (online)
ID: 378929011
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520 3 |a Calibration in analytical chemistry refers to the relation between sample domain and measurement domain (signal domain) expressed by an analytical function x = fs(Q) representing a pattern of chemical species Q and their amounts or concentrations x in a given test sample on the one hand and a measured function y = f(z) that may be a spectrum, chromatogram, etc. Simultaneous multispecies analyses are carried out mainly by spectroscopic and chromatographic methods in a more or less selective way. For the determination of n species Qi (i = 1,2 ...n), at least n signals must be measured which should be well separated in the ideal case. In analytical practice, the situation can be different. 
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