Complex formation of uranium(VI) in periodate solutions
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| 024 | 7 | 0 | |a 10.1524/ract.92.8.489.39277 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/ract.92.8.489.39277 | ||
| 245 | 0 | 0 | |a Complex formation of uranium(VI) in periodate solutions |h [Elektronische Daten] |c [M. Karbowiak, S. Hubert, B. Fourest, Christophe Moulin] |
| 520 | 3 | |a The uranyl/periodate system was investigated by Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLIFS), and Capillary Electrophoresis (CE) in 0.1 and 0.05molL-1 perchloric solutions at pH 2.6, containing various amounts of periodate anions. The formation of only one complex, UO2IO4+, was observed for a periodate concentration ranging from 5×10-5 to 10-1molL-1. The stability constant of this complex was estimated to be log β11=1.8±0.2 by TRLIFS (fluorescence titration) and log β11=2.0±0.2 by CE, for an ionic strength of 10-1 and 5×10-2molL-1, respectively. Moreover, the 1:1 stoichiometrical ratio between uranium(VI) and periodate was confirmed by an analysis of the results obtained from the deconvolution of fluorescence spectra. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Analytical chemistry |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 700 | 1 | |a Karbowiak |D M. |4 aut | |
| 700 | 1 | |a Hubert |D S. |4 aut | |
| 700 | 1 | |a Fourest |D B. |4 aut | |
| 700 | 1 | |a Moulin |D Christophe |4 aut | |
| 773 | 0 | |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 92/8/2004(2004-08-01), 489-494 |x 0033-8230 |q 92:8/2004<489 |1 2004 |2 92 |o ract | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/ract.92.8.489.39277 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/ract.92.8.489.39277 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Karbowiak |D M. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Hubert |D S. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Fourest |D B. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Moulin |D Christophe |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Radiochimica Acta/International journal for chemical aspects of nuclear science and technology |d Oldenbourg Wissenschaftsverlag GmbH |g 92/8/2004(2004-08-01), 489-494 |x 0033-8230 |q 92:8/2004<489 |1 2004 |2 92 |o ract | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||