Ultra-Microelectrode Voltammetric Measurement of the Hydrodynamic Radii and Shear Plane of Micellar Particles for Sodium Dodecyl Sulfate in Aqueous NaCl Solutions
Gespeichert in:
Verfasser / Beitragende:
[Zhenyu Yang, Jinsheng Zhao, Yu Xie, Xiuli Yin, Zhankui Du, Zhengyu Yang]
Ort, Verlag, Jahr:
2004
Enthalten in:
Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics, 218/2/2004(2004-02-01), 201-210
Format:
Artikel (online)
Online Zugang:
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| 008 | 161128e20040201xx s 000 0 eng | ||
| 024 | 7 | 0 | |a 10.1524/zpch.218.2.201.25922 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zpch.218.2.201.25922 | ||
| 245 | 0 | 0 | |a Ultra-Microelectrode Voltammetric Measurement of the Hydrodynamic Radii and Shear Plane of Micellar Particles for Sodium Dodecyl Sulfate in Aqueous NaCl Solutions |h [Elektronische Daten] |c [Zhenyu Yang, Jinsheng Zhao, Yu Xie, Xiuli Yin, Zhankui Du, Zhengyu Yang] |
| 520 | 3 | |a Ultra-microelectrode voltammetric measurements have been performed on sodium dodecyl sulfate (SDS) in the aqueous NaCl solutions at 298.2 ± 0.1K. The hydrodynamic radii (Rh0) of micellar particles are calculated. The results suggest that Rh0 decrease initially due to collapse of the shear plane toward the micelle hard-sphere surface, and then Rh0 increase gradually due to electrolyte-induced linear spherical expansion of the micellar particles. Based on it, the location of micellar shear plane, the relationship between the shear plane and Debye-Hückel length, and the associated ζ-potential are also estimated. It is found that the relationship between the shear plane and Debye-Hückel length is linear, and, in different NaCl concentrations, the shear plane is almost located at a constant shear potential of 77 ± 10mV, close to the hard-sphere surface of SDS micelle particles. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Thermodynamics & statistical physics |2 nationallicence | |
| 690 | 7 | |a Laboratory techniques, experiments |2 nationallicence | |
| 690 | 7 | |a Physical chemistry |2 nationallicence | |
| 700 | 1 | |a Yang |D Zhenyu |4 aut | |
| 700 | 1 | |a Zhao |D Jinsheng |4 aut | |
| 700 | 1 | |a Xie |D Yu |4 aut | |
| 700 | 1 | |a Yin |D Xiuli |4 aut | |
| 700 | 1 | |a Du |D Zhankui |4 aut | |
| 700 | 1 | |a Yang |D Zhengyu |4 aut | |
| 773 | 0 | |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/2/2004(2004-02-01), 201-210 |x 0942-9352 |q 218:2/2004<201 |1 2004 |2 218 |o zpch | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zpch.218.2.201.25922 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zpch.218.2.201.25922 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yang |D Zhenyu |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Zhao |D Jinsheng |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Xie |D Yu |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yin |D Xiuli |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Du |D Zhankui |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Yang |D Zhengyu |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics |d Oldenbourg Wissenschaftsverlag GmbH |g 218/2/2004(2004-02-01), 201-210 |x 0942-9352 |q 218:2/2004<201 |1 2004 |2 218 |o zpch | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||