caa a22 4500 378932373 CHVBK 20180305123633.0 cr unu---uuuuu 161128e20041001xx s 000 0 eng 10.1524/zpch.218.10.1147.43592 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.10.1147.43592 Drescher Markus Time-Resolved ESCA: a Novel Probe for Chemical Dynamics [Elektronische Daten] [Markus Drescher] Electron spectroscopy for chemical analysis (ESCA) is a well established tool for quantitative studies of the composition and the chemical environment of molecular systems. Recent developments in the generation and utilization of ultrashort X-ray pulses now add the dimension of time to this technique and will expand the possibilities of femtochemistry in terms of chemical selectivity, quality of information, and temporal resolution. The properties and capabilities of various X-ray pulse sources are discussed, along with their prospects for dynamical studies. Examples of time-resolved electron spectroscopy are presented in the femtosecond (1fs = 10−15s) as well as the attosecond (1as = 10−18s) regime, the latter marking the current ultimate limit for the time-resolution in pump-probe experiments. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/10/2004(2004-10-01), 1147-1168 0942-9352 218:10/2004<1147 2004 218 zpch https://doi.org/10.1524/zpch.218.10.1147.43592 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.10.1147.43592 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Drescher Markus NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/10/2004(2004-10-01), 1147-1168 0942-9352 218:10/2004<1147 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter