Palladium-catalyzed arylation of linear and cyclic polyamines
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| 024 | 7 | 0 | |a 10.1351/pac200476091605 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1351/pac200476091605 | ||
| 245 | 0 | 0 | |a Palladium-catalyzed arylation of linear and cyclic polyamines |h [Elektronische Daten] |c [Irina P. Beletskaya, A. D. Averin] |
| 520 | 3 | |a Synthetic protocols for the palladium-catalyzed arylation of various linear and cyclic polyamines and polyoxapolyamines has been worked out. Pd(0) and Pd(II)complexes with such phosphine ligands as dppf, BINAP, PPF-OMe, P(tBu)3,2-ditert-butylphosphino-1,1'-biphenyl have been explored in the catalytic amination reactions. Monoamination of chloro-, bromo-, and iodoarenes with di-, tri-, and tetraamines have been carried out, conditions for di- and polyarylation of linear polyamines have been elaborated. Successful arylation of 1,4,7,10-tetraazacyclododecane (cyclene) and 1,4,8,11-tetraazacyclotetradecane (cyclam) have been conducted. Intramolecular diamination of dihaloarenes such as 1,2-dibromobenzene, 2,6-dichlorobromobenzene, 1,3-dibromobenzene, 1,8-dichloroanthracene, 1,8-dichloroanthraquinone, 1,5-dichloroanthracene, and 1,5-dichloroanthraquinone afforded corresponding polyazamacrocycles containing arene moieties. For the first time, a convenient one-pot synthesis of the face-to-face arranged bismacrocyclic systems has been carried out. | |
| 540 | |a © 2013 Walter de Gruyter GmbH, Berlin/Boston | ||
| 700 | 1 | |a Beletskaya |D Irina P. |u Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia |4 aut | |
| 700 | 1 | |a Averin |D A. D. |u Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia |4 aut | |
| 773 | 0 | |t Pure and Applied Chemistry |d De Gruyter |g 76/9(2004-09-30), 1605-1619 |x 0033-4545 |q 76:9<1605 |1 2004 |2 76 |o pac | |
| 856 | 4 | 0 | |u https://doi.org/10.1351/pac200476091605 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1351/pac200476091605 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Beletskaya |D Irina P. |u Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Averin |D A. D. |u Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Pure and Applied Chemistry |d De Gruyter |g 76/9(2004-09-30), 1605-1619 |x 0033-4545 |q 76:9<1605 |1 2004 |2 76 |o pac | ||
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| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||