caa a22 4500 378939203 CHVBK 20180305123648.0 cr unu---uuuuu 161128e20040930xx s 000 0 eng 10.1351/pac200476091605 doi (NATIONALLICENCE)gruyter-10.1351/pac200476091605 Palladium-catalyzed arylation of linear and cyclic polyamines [Elektronische Daten] [Irina P. Beletskaya, A. D. Averin] Synthetic protocols for the palladium-catalyzed arylation of various linear and cyclic polyamines and polyoxapolyamines has been worked out. Pd(0) and Pd(II)complexes with such phosphine ligands as dppf, BINAP, PPF-OMe, P(tBu)3,2-ditert-butylphosphino-1,1'-biphenyl have been explored in the catalytic amination reactions. Monoamination of chloro-, bromo-, and iodoarenes with di-, tri-, and tetraamines have been carried out, conditions for di- and polyarylation of linear polyamines have been elaborated. Successful arylation of 1,4,7,10-tetraazacyclododecane (cyclene) and 1,4,8,11-tetraazacyclotetradecane (cyclam) have been conducted. Intramolecular diamination of dihaloarenes such as 1,2-dibromobenzene, 2,6-dichlorobromobenzene, 1,3-dibromobenzene, 1,8-dichloroanthracene, 1,8-dichloroanthraquinone, 1,5-dichloroanthracene, and 1,5-dichloroanthraquinone afforded corresponding polyazamacrocycles containing arene moieties. For the first time, a convenient one-pot synthesis of the face-to-face arranged bismacrocyclic systems has been carried out. © 2013 Walter de Gruyter GmbH, Berlin/Boston Beletskaya Irina P. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia aut Averin A. D. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia aut Pure and Applied Chemistry De Gruyter 76/9(2004-09-30), 1605-1619 0033-4545 76:9<1605 2004 76 pac https://doi.org/10.1351/pac200476091605 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1351/pac200476091605 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Beletskaya Irina P. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia aut NATIONALLICENCE 700 1- Averin A. D. Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory, Moscow 119992, Russia aut NATIONALLICENCE 773 0- Pure and Applied Chemistry De Gruyter 76/9(2004-09-30), 1605-1619 0033-4545 76:9<1605 2004 76 pac CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter