X-ray and VIS light scattering from light-induced polymer gratings

Verfasser / Beitragende:
[Oliver Henneberg, Tobias Panzner, Ullrich Pietsch, Thomas Geue, Marina Saphiannikova, Paul Rochon, Ken Finkelstein]
Ort, Verlag, Jahr:
2004
Enthalten in:
Zeitschrift für Kristallographie - Crystalline Materials, 219/4(2004-04-01), 218-223
Format:
Artikel (online)
ID: 378939572
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024 7 0 |a 10.1524/zkri.219.4.218.30438  |2 doi 
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245 0 0 |a X-ray and VIS light scattering from light-induced polymer gratings  |h [Elektronische Daten]  |c [Oliver Henneberg, Tobias Panzner, Ullrich Pietsch, Thomas Geue, Marina Saphiannikova, Paul Rochon, Ken Finkelstein] 
520 3 |a Sinusoidally shaped surface relief gratings made of polymer films containing azobenzene moieties can be created by holographic illumination with laser light of about λ ≈ 500 nm. The remarkable material transport takes place at temperatures far (100 K) below the glass transition temperature of the material. As probed by visible light scattering the efficiency of grating formation crucially depends on the polarization state of the laser light and is maximal when circular polarization is used. In contrast to VIS light scattering X-ray diffraction is most sensitive for periodic surface undulations with amplitudes below 10 nm. Thus, combined in-situ X-ray and visible light scattering at CHESS were used to investigate the dynamics of surface relief grating formations upon laser illumination. The time development of grating peaks up to 9th order at laser power of P = 20 mW/cm2 could be investigated, even the onset of grating formation as a function of light polarization. A linear growth of grating amplitude was observed for all polarizations. The growth velocity is maximal using circularly polarized light but very small for s-polarized light. 
540 |a © 2004 Oldenbourg Wissenschaftsverlag GmbH 
690 7 |a Crystallography  |2 nationallicence 
690 7 |a Inorganic chemistry  |2 nationallicence 
690 7 |a Organic chemistry  |2 nationallicence 
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700 1 |a Saphiannikova  |D Marina  |4 aut 
700 1 |a Rochon  |D Paul  |4 aut 
700 1 |a Finkelstein  |D Ken  |4 aut 
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