caa a22 4500 378942514 CHVBK 20180305123656.0 cr unu---uuuuu 161128e20040301xx s 000 0 eng 10.1524/zpch.218.3.349.26494 doi (NATIONALLICENCE)gruyter-10.1524/zpch.218.3.349.26494 Thermodynamics of the Interaction between Electrolyte (CaCl2, NaCl, NaBr, NaI) and Monosaccharide (D-mannose, D-ribose) in Water at 298.15K [Elektronische Daten] [Lixia Yang, Kelei Zhuo, Yang Zhao, Jianji Wang] Electrochemical cells with a cation selective electrode (Ca-ISE, Na-ISE) versus an anion selective electrode (Cl-ISE, Br-ISE, I-ISE) as a reference electrode were used to determine the activity coefficients for electrolyte (CaCl2, NaCl, NaBr and NaI)-monosaccharide (D-mannose, D-ribose) systems in water at 298.15K. The Gibbs free energy interaction parameters and salting constants were also evaluated. The results showed that the interaction of ribose is stronger than that of mannose with these electrolytes, and the interaction of calcium ion is stronger than that of sodium ion with these monosaccharides. These were discussed in terms of the stereochemistry of saccharide molecules and the structural interaction model. © 2004 Oldenbourg Wissenschaftsverlag GmbH Thermodynamics & statistical physics nationallicence Laboratory techniques, experiments nationallicence Physical chemistry nationallicence Yang Lixia aut Zhuo Kelei aut Zhao Yang aut Wang Jianji aut Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/3/2004(2004-03-01), 349-362 0942-9352 218:3/2004<349 2004 218 zpch https://doi.org/10.1524/zpch.218.3.349.26494 text/html Onlinezugriff via DOI 1 research article jats NATIONALLICENCE 856 40 https://doi.org/10.1524/zpch.218.3.349.26494 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Yang Lixia aut NATIONALLICENCE 700 1- Zhuo Kelei aut NATIONALLICENCE 700 1- Zhao Yang aut NATIONALLICENCE 700 1- Wang Jianji aut NATIONALLICENCE 773 0- Zeitschrift für Physikalische Chemie/International journal of research in physical chemistry and chemical physics Oldenbourg Wissenschaftsverlag GmbH 218/3/2004(2004-03-01), 349-362 0942-9352 218:3/2004<349 2004 218 zpch CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-gruyter