Low-temperature crystal structure of RS-thiocamphor
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| 024 | 7 | 0 | |a 10.1524/zkri.219.9.580.44038 |2 doi |
| 035 | |a (NATIONALLICENCE)gruyter-10.1524/zkri.219.9.580.44038 | ||
| 245 | 0 | 0 | |a Low-temperature crystal structure of RS-thiocamphor |h [Elektronische Daten] |c [E. Louise R. Robins, Michela Brunelli, Asiloé J. Mora, Andrew N. Fitch] |
| 520 | 3 | |a DSC and high-resolution powder X-ray diffraction measurements in the range 295 K-100 K show that RS-thiocamphor undergoes two phase transitions. The first, at around 260 K on cooling, is from the room-temperature body-centred-cubic phase to a short-lived intermediate. At 258 K the low-temperature form starts to appear. The crystal structure of the latter is orthorhombic, space group Pbnm, with a = 9.0643(4) Å, b = 14.6714(8) Å, c = 7.2878(4) Å, Z = 4, ρcalc = 1.15 g cm-3 at 100 K. The structure is two-fold disordered, with the enantiomers superimposed in the average structure, related by the mirror plane. | |
| 540 | |a © 2004 Oldenbourg Wissenschaftsverlag GmbH | ||
| 690 | 7 | |a Crystallography |2 nationallicence | |
| 690 | 7 | |a Inorganic chemistry |2 nationallicence | |
| 690 | 7 | |a Organic chemistry |2 nationallicence | |
| 700 | 1 | |a Robins |D E. Louise R. |4 aut | |
| 700 | 1 | |a Brunelli |D Michela |4 aut | |
| 700 | 1 | |a Mora |D Asiloé J. |4 aut | |
| 700 | 1 | |a Fitch |D Andrew N. |4 aut | |
| 773 | 0 | |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/9(2004-09-01), 580-583 |x 2194-4946 |q 219:9<580 |1 2004 |2 219 |o zkri | |
| 856 | 4 | 0 | |u https://doi.org/10.1524/zkri.219.9.580.44038 |q text/html |z Onlinezugriff via DOI |
| 908 | |D 1 |a research article |2 jats | ||
| 950 | |B NATIONALLICENCE |P 856 |E 40 |u https://doi.org/10.1524/zkri.219.9.580.44038 |q text/html |z Onlinezugriff via DOI | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Robins |D E. Louise R. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Brunelli |D Michela |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Mora |D Asiloé J. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 700 |E 1- |a Fitch |D Andrew N. |4 aut | ||
| 950 | |B NATIONALLICENCE |P 773 |E 0- |t Zeitschrift für Kristallographie - Crystalline Materials |d De Gruyter Oldenbourg |g 219/9(2004-09-01), 580-583 |x 2194-4946 |q 219:9<580 |1 2004 |2 219 |o zkri | ||
| 900 | 7 | |b CC0 |u http://creativecommons.org/publicdomain/zero/1.0 |2 nationallicence | |
| 898 | |a BK010053 |b XK010053 |c XK010000 | ||
| 949 | |B NATIONALLICENCE |F NATIONALLICENCE |b NL-gruyter | ||