caa a22 4500 388019867 CHVBK 20180307124921.0 cr unu---uuuuu 161130e199804 xx s 000 0 eng 10.1557/JMR.1998.0128 doi S088429140004365X pii (NATIONALLICENCE)cambridge-10.1557/JMR.1998.0128 A kaolinite-NMF-methanol intercalation compound as a versatile intermediate for further intercalation reaction of kaolinite [Elektronische Daten] A kaolinite-organic intercalation compound containing methanol was proved to be a versatile host for further displacement reaction with alkylamines. Kaolinite-organic intercalation compounds with polar molecules, such as N-methylformamide (NMF) and formamide, were used as the starting materials. After stirring the kaolinite-NMF intercalation compound with methanol, the basal spacing increased to 1.11 nm. The 13C MAS NMR result of the product indicated that methanol was intercalated into kaolinite by partial displacement with NMF. By use of the methanol-treated kaolinite intercalation compound as the intermediate, alkylamines were intercalated into the interlayer space of kaolinite by displacing with methanol. Copyright © Materials Research Society 1998 Komori Yoshihiko Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan Sugahara Yoshiyuki Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan Kuroda Kazuyuki Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan, and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo 169, Japan Journal of Materials Research Cambridge University Press 13/4(1998-04), 930-934 0884-2914 13:4<930 1998 13 JMR https://doi.org/10.1557/JMR.1998.0128 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1557/JMR.1998.0128 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Komori Yoshihiko Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan NATIONALLICENCE 700 1- Sugahara Yoshiyuki Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan NATIONALLICENCE 700 1- Kuroda Kazuyuki Department of Applied Chemistry, School of Science and Engineering, Waseda University, Ohkubo-3, Shinjuku-ku, Tokyo 169, Japan, and Kagami Memorial Laboratory for Materials Science and Technology, Waseda University, Nishiwaseda-2, Shinjuku-ku, Tokyo 169, Japan NATIONALLICENCE 773 0- Journal of Materials Research Cambridge University Press 13/4(1998-04), 930-934 0884-2914 13:4<930 1998 13 JMR CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-cambridge