caa a22 4500 388021233 CHVBK 20180307124925.0 cr unu---uuuuu 161130e199801 xx s 000 0 eng 10.1557/JMR.1998.0029 doi S0884291400042667 pii (NATIONALLICENCE)cambridge-10.1557/JMR.1998.0029 Initial stages of silicate growth on and oxidation of graphite: A model for composites [Elektronische Daten] The initial stages of silicate growth on graphite are characterized with atomic force microscopy. The morphological development indicates that decomposition of tetra ethyloxysilane at low pressure produces films of 3 nm clusters located at undercoordinated carbon sites. Clusters eventually cover the surface, at which point a second layer grows. In higher pressure deposition multiple layers of clusters grow simultaneously. A comparison of the oxidation behavior of surfaces with defects completely and incompletely terminated with SiOx shows that edge recession is the primary oxidation mechanism and that the site specificity of SiOx is effective in inhibiting oxidation. Copyright © Materials Research Society 1998 Bonnell Dawn A. Department of Materials Science and Engineering, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 Jiron Darrin Department of Materials Science and Engineering, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 Flinn Timothy Department of Materials Science and Engineering, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 Journal of Materials Research Cambridge University Press 13/1(1998-01), 217-222 0884-2914 13:1<217 1998 13 JMR https://doi.org/10.1557/JMR.1998.0029 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1557/JMR.1998.0029 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bonnell Dawn A. Department of Materials Science and Engineering, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 NATIONALLICENCE 700 1- Jiron Darrin Department of Materials Science and Engineering, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 NATIONALLICENCE 700 1- Flinn Timothy Department of Materials Science and Engineering, The University of Pennsylvania, Philadelphia, Pennsylvania 19104 NATIONALLICENCE 773 0- Journal of Materials Research Cambridge University Press 13/1(1998-01), 217-222 0884-2914 13:1<217 1998 13 JMR CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-cambridge