caa a22 4500 388021659 CHVBK 20180307124926.0 cr unu---uuuuu 161130e199802 xx s 000 0 eng 10.1557/JMR.1998.0044 doi S0884291400042813 pii (NATIONALLICENCE)cambridge-10.1557/JMR.1998.0044 Hydrothermal preparation of the mixed titanium (IV) phosphate-phenylphosphonates and characterization of their properties [Elektronische Daten] Mixed crystalline titanium (IV) phosphate-phenylphosphonates were synthesized under hydrothermal conditions using tetramethylammonium hydroxide as a templating reagent. It was found that at a relatively low molar ratio H3PO4 : PhPO3H2 in the reaction mixture (<1) only a pure α-titanium phenylphosphonate is formed. At the molar ratio H3PO4 : PhPO3H2 = (3-5): 1 the formation of a novel mixed compound titanium (IV) dihydrogenphosphate-hydrogenphosphate-phenylphosphonate takes place. Further increase of the ratio H3PO4 : PhPO3H2 gives mechanical mixtures of different phases. Preliminary results on the characterization of the novel compound of formula Ti(H2PO4)1.25(HPO4)0.12(C6H5PO3)1.25 · 0.3H2O are presented. Copyright © Materials Research Society 1998 Jaimez Enrique Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain Bortun Anatoly I. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain Khainakov Sergei A. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain Voitko Igor' I. Department of Chemistry, Kiev State Trade and Economic University, 19 Kyoto Str., 252156, Kiev, Ukraine García José R. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain Rodríguez Julio Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain Journal of Materials Research Cambridge University Press 13/2(1998-02), 323-328 0884-2914 13:2<323 1998 13 JMR https://doi.org/10.1557/JMR.1998.0044 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1557/JMR.1998.0044 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Jaimez Enrique Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain NATIONALLICENCE 700 1- Bortun Anatoly I. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain NATIONALLICENCE 700 1- Khainakov Sergei A. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain NATIONALLICENCE 700 1- Voitko Igor' I. Department of Chemistry, Kiev State Trade and Economic University, 19 Kyoto Str., 252156, Kiev, Ukraine NATIONALLICENCE 700 1- García José R. Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain NATIONALLICENCE 700 1- Rodríguez Julio Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, 33071 Oviedo, Spain NATIONALLICENCE 773 0- Journal of Materials Research Cambridge University Press 13/2(1998-02), 323-328 0884-2914 13:2<323 1998 13 JMR CC0 http://creativecommons.org/publicdomain/zero/1.0 nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-cambridge