caa a22 4500 445325763 CHVBK 20180317142720.0 cr unu---uuuuu 170323e20110701xx s 000 0 eng 10.1007/s10858-011-9516-2 doi (NATIONALLICENCE)springer-10.1007/s10858-011-9516-2 Chemical shift correlation at high MAS frequencies employing low-power symmetry-based mixing schemes [Elektronische Daten] [Christian Herbst, Jirada Herbst, Jörg Leppert, Oliver Ohlenschläger, Matthias Görlach, Ramadurai Ramachandran] An approach for conveniently implementing low-power CN n ν and RN n ν symmetry-based band-selective mixing sequences for generating homo- and heteronuclear chemical shift correlation NMR spectra of low γ nuclei in biological solids is demonstrated. Efficient magnetisation transfer characteristics are achieved by selecting appropriate symmetries requiring the application of basic RF elements of relatively long duration and numerically tailoring the RF field modulation profile of the basic element. The efficacy of the approach is experimentally shown by the acquisition of 15N-13C dipolar and 13C-13C scalar and dipolar coupling mediated chemical shift correlation spectra at representative MAS frequencies. Springer Science+Business Media B.V., 2011 Solid-state NMR spectroscopy nationallicence 15N-13C and 13C-13C dipolar recoupling nationallicence 13C-13C scalar recoupling nationallicence Symmetry-based pulse sequences nationallicence Herbst Christian Department of Physics; Faculty of Science, Ubon Ratchathani University, 34190, Ubon Ratchathani, Thailand aut Herbst Jirada Department of Mathematics, Statistics and Computer, Faculty of Science, Ubon Ratchathani University, 34190, Ubon Ratchathani, Thailand aut Leppert Jörg Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut Ohlenschläger Oliver Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut Görlach Matthias Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut Ramachandran Ramadurai Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut Journal of Biomolecular NMR Springer Netherlands 50/3(2011-07-01), 277-284 0925-2738 50:3<277 2011 50 10858 https://doi.org/10.1007/s10858-011-9516-2 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10858-011-9516-2 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Herbst Christian Department of Physics; Faculty of Science, Ubon Ratchathani University, 34190, Ubon Ratchathani, Thailand aut NATIONALLICENCE 700 1- Herbst Jirada Department of Mathematics, Statistics and Computer, Faculty of Science, Ubon Ratchathani University, 34190, Ubon Ratchathani, Thailand aut NATIONALLICENCE 700 1- Leppert Jörg Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut NATIONALLICENCE 700 1- Ohlenschläger Oliver Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut NATIONALLICENCE 700 1- Görlach Matthias Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut NATIONALLICENCE 700 1- Ramachandran Ramadurai Research group Biomolecular NMR spectroscopy, Leibniz Institute for Age Research, Fritz Lipmann Institute, 07745, Jena, Germany aut NATIONALLICENCE 773 0- Journal of Biomolecular NMR Springer Netherlands 50/3(2011-07-01), 277-284 0925-2738 50:3<277 2011 50 10858 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer