caa a22 4500 44532595X CHVBK 20180317142720.0 cr unu---uuuuu 170323e20110601xx s 000 0 eng 10.1007/s10858-011-9501-9 doi (NATIONALLICENCE)springer-10.1007/s10858-011-9501-9 Sensitive 13C-13C correlation spectra of amyloid fibrils at very high spinning frequencies and magnetic fields [Elektronische Daten] [Markus Weingarth, Yuichi Masuda, K. Takegoshi, Geoffrey Bodenhausen, Piotr Tekely] Sensitive 2D solid-state 13C-13C correlation spectra of amyloid β fibrils have been recorded at very fast spinning frequencies and very high magnetic fields. It is demonstrated that PARIS-xy recoupling using moderate rf amplitudes can provide structural information by promoting efficient magnetization transfer even under such challenging experimental conditions. Furthermore, it has been shown both experimentally and by numerical simulations that the method is not very sensitive to dipolar truncation effects and can reveal direct transfer across distances of about 3.5-4Å. Springer Science+Business Media B.V., 2011 Amyloid β fibrils nationallicence Solid-state NMR nationallicence 13C-13C 2D correlation spectra nationallicence Dipolar truncation nationallicence PARIS-xy dipolar recoupling nationallicence Ultra-high magnetic field nationallicence Weingarth Markus Département de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75231, Paris, France aut Masuda Yuichi Department of Chemistry, Graduate School of Science, Kyoto University, 606-8502, Kyoto, Japan aut Takegoshi K. Department of Chemistry, Graduate School of Science, Kyoto University, 606-8502, Kyoto, Japan aut Bodenhausen Geoffrey Département de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75231, Paris, France aut Tekely Piotr Département de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75231, Paris, France aut Journal of Biomolecular NMR Springer Netherlands 50/2(2011-06-01), 129-136 0925-2738 50:2<129 2011 50 10858 https://doi.org/10.1007/s10858-011-9501-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10858-011-9501-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Weingarth Markus Département de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75231, Paris, France aut NATIONALLICENCE 700 1- Masuda Yuichi Department of Chemistry, Graduate School of Science, Kyoto University, 606-8502, Kyoto, Japan aut NATIONALLICENCE 700 1- Takegoshi K. Department of Chemistry, Graduate School of Science, Kyoto University, 606-8502, Kyoto, Japan aut NATIONALLICENCE 700 1- Bodenhausen Geoffrey Département de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75231, Paris, France aut NATIONALLICENCE 700 1- Tekely Piotr Département de Chimie, Ecole Normale Supérieure, 24 rue Lhomond, 75231, Paris, France aut NATIONALLICENCE 773 0- Journal of Biomolecular NMR Springer Netherlands 50/2(2011-06-01), 129-136 0925-2738 50:2<129 2011 50 10858 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer