caa a22 4500 44532743X CHVBK 20180317142725.0 cr unu---uuuuu 170323e20110101xx s 000 0 eng 10.1007/s10953-010-9621-y doi (NATIONALLICENCE)springer-10.1007/s10953-010-9621-y Volumetric Properties of Some Aliphatic Mono- andDicarboxylic Acids inWater at298.15K [Elektronische Daten] [Adam Bald, Zdzisław Kinart] The apparent molar volumes, V φ, of two series of homologous aliphatic carboxylic acids, H(CH2)nCOOH [n=0-5] and (CH2)n(COOH)2 [n=0-5], were determined in dilute aqueous solutions by density measurements at T=298.15K. Densities were measured using a vibrating-tube densimeter (DMA 5000, Anton Paar, Austria) at T=298.15K. These results were used to calculate the apparent molar volumes of each solute over the concentration range 0.0050≤m/(mol⋅kg−1)≤0.3000. Values of the apparent molar volumes of undissociated acids $V_{\phi (u)}^{0}$ were also calculated. The variation of $V_{\phi (u)}^{0}$ was determined as a function of the aliphatic chain length of the studied carboxylic acids. The Author(s), 2010 Carboxylic acid nationallicence Apparent molar volume nationallicence Water nationallicence Bald Adam Department of Physical Chemistry of Solutions, University of Lodz, ul. Pomorska 163, 90-236, Lodz, Poland aut Kinart Zdzisław Department of Physical Chemistry of Solutions, University of Lodz, ul. Pomorska 163, 90-236, Lodz, Poland aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/1(2011-01-01), 1-16 0095-9782 40:1<1 2011 40 10953 https://doi.org/10.1007/s10953-010-9621-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-010-9621-y text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bald Adam Department of Physical Chemistry of Solutions, University of Lodz, ul. Pomorska 163, 90-236, Lodz, Poland aut NATIONALLICENCE 700 1- Kinart Zdzisław Department of Physical Chemistry of Solutions, University of Lodz, ul. Pomorska 163, 90-236, Lodz, Poland aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/1(2011-01-01), 1-16 0095-9782 40:1<1 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer