caa a22 4500 445327707 CHVBK 20180317142726.0 cr unu---uuuuu 170323e20110901xx s 000 0 eng 10.1007/s10953-011-9734-y doi (NATIONALLICENCE)springer-10.1007/s10953-011-9734-y Aupiais J. DAM DIF, CEA, 91297, Arpajon Cedex, France aut Electrophoretic Mobilities of the Isotopes of Chloride and Bromide Ions in Aqueous Solution at 25 °C and Infinite Dilution [Elektronische Daten] [J. Aupiais] The electrophoretic mobilities of a few halide isotopes in aqueous solution have been evaluated at 25 °C and infinite dilution by analyzing a combination of data obtained by capillary electrophoresis (CE) and conductance data extracted from the literature. The effect of the temperature on the electrophoretic mobility has been thoroughly re-investigated to give the following temperature dependence for the chloride ion at 25 °C: 1.565%/ °C in 5×10−3mol⋅L−1 sodium chromate + 3×10−3mol⋅L−1 sodium borate buffer. The precise determination of the electrophoretic mobility of chloride and bromide ions, including the evaluation of their associated uncertainties, has been performed from conductance data spanning over 75years. The electrophoretic mobilities are found to be −(79.124±0.020)×10−9m2⋅V−1⋅s−1 for Cl− and −(80.99±0.04)×10−9m2⋅V−1⋅s−1 for Br−. Thanks to the precise determination of the temperature contribution and the re-evaluation of conductance data, the following values have been found for 35Cl−, 37Cl−, 79Br−, and 81Br− (in 10−9m2⋅V−1⋅s−1): −(79.18±0.02), −(78.95±0.06), −(81.04±0.04), and −(80.94±0.04). Springer Science+Business Media, LLC, 2011 Halogen isotopes nationallicence Electrophoretic mobility nationallicence Isotopic separation nationallicence Limiting molar conductivity nationallicence Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/9(2011-09-01), 1629-1644 0095-9782 40:9<1629 2011 40 10953 https://doi.org/10.1007/s10953-011-9734-y text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9734-y text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Aupiais J. DAM DIF, CEA, 91297, Arpajon Cedex, France aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/9(2011-09-01), 1629-1644 0095-9782 40:9<1629 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer