caa a22 4500 445327758 CHVBK 20180317142726.0 cr unu---uuuuu 170323e20110901xx s 000 0 eng 10.1007/s10953-011-9743-x doi (NATIONALLICENCE)springer-10.1007/s10953-011-9743-x Topological and Thermodynamic Studies for Binary Mixtures of 1,4-Dioxane with Anilines at 308.15 K [Elektronische Daten] [V. Sharma, Sunil Jangra, Neeti Saini, Jaibir Yadav, Dimple Sharma] Excess molar volumes, V E, excess molar enthalpies, H E, speeds of sound, u, and vapor-liquid equilibrium data of 1,4-dioxane (1) + aniline or N-methyl aniline or o-toluidine (2) binary mixtures have been measured as a function of composition at 308.15 K. Isentropic compressibility changes that occur for mixing, $\kappa_{S}^{\mathrm{E}}$ , and excess Gibb's energies, G E, have been determined by employing speeds of sound and vapor-liquid equilibrium data. The $V^{\mathrm{E}}, H^{\mathrm{E}},\kappa_{S}^{\mathrm{E}}$ and G E values have been estimated by (i) graph theory and (ii) the Prigonone-Flory-Patterson theory (PFP). It was observed that values of $V^{\mathrm{E}}, H^{\mathrm{E}},\kappa_{S}^{\mathrm{E}}$ and G E predicted by graph theory compare well, relative to the PFP theory, with their corresponding experimental values. Springer Science+Business Media, LLC, 2011 Excess molar enthalpy H E nationallicence Excess Gibbs energy G E nationallicence Excess molar volume V E nationallicence Isentropic compressibility changes for mixing $\kappa_{S}^{\mathrm{E}}$ nationallicence Interaction parameters nationallicence Sharma V. Department of Chemistry, Maharshi Dayanand University, 124001, Rohtak, India aut Jangra Sunil Department of Chemistry, Maharshi Dayanand University, 124001, Rohtak, India aut Saini Neeti Department of Chemistry, Maharshi Dayanand University, 124001, Rohtak, India aut Yadav Jaibir Department of Chemistry, A.I.J.H.M. College, 124001, Rohtak, Haryana, India aut Sharma Dimple P.D.M. College of Engineering for Women, Bhadurgarh, Haryana, India aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/9(2011-09-01), 1563-1581 0095-9782 40:9<1563 2011 40 10953 https://doi.org/10.1007/s10953-011-9743-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9743-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Sharma V. Department of Chemistry, Maharshi Dayanand University, 124001, Rohtak, India aut NATIONALLICENCE 700 1- Jangra Sunil Department of Chemistry, Maharshi Dayanand University, 124001, Rohtak, India aut NATIONALLICENCE 700 1- Saini Neeti Department of Chemistry, Maharshi Dayanand University, 124001, Rohtak, India aut NATIONALLICENCE 700 1- Yadav Jaibir Department of Chemistry, A.I.J.H.M. College, 124001, Rohtak, Haryana, India aut NATIONALLICENCE 700 1- Sharma Dimple P.D.M. College of Engineering for Women, Bhadurgarh, Haryana, India aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/9(2011-09-01), 1563-1581 0095-9782 40:9<1563 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer