caa a22 4500 445327790 CHVBK 20180317142726.0 cr unu---uuuuu 170323e20110701xx s 000 0 eng 10.1007/s10953-011-9711-5 doi (NATIONALLICENCE)springer-10.1007/s10953-011-9711-5 Partial Molar Volumes and Refractions of Aqueous Solutions of Poly[vinyl alcohol] [Elektronische Daten] [A. Fucaloro, C. Edmunds, S. Grant, W. Kim, B. Lee, J. Mao, G. Pera, K. Pinnock] The partial molar volumes (V 2) and refractions (R 2) for poly[vinyl alcohol] (PVOH) in water were determined at 0.00, 5.00, 15.00, 20.00, and 25.00 °C. Each of the partial molar quantities exhibits a small but significant dependence upon concentration which is analyzed using a previously reported model of solvation. This study concludes that the water in the regions surrounding the solute molecules exhibits less hydrogen bonding and as a consequence is denser than the bulk water. In addition, the study finds that the partial molar volume of PVOH at infinite dilution is the simple sum of contributions from its monomer units (-CH2-CHOH-). Springer Science+Business Media, LLC, 2011 Poly[vinyl alcohol] nationallicence Polymer nationallicence Molar volume nationallicence Partial molar volume nationallicence Molar refraction nationallicence Partial molar refraction nationallicence Fucaloro A. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Edmunds C. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Grant S. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Kim W. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Lee B. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Mao J. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Pera G. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Pinnock K. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/7(2011-07-01), 1349-1360 0095-9782 40:7<1349 2011 40 10953 https://doi.org/10.1007/s10953-011-9711-5 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9711-5 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Fucaloro A. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Edmunds C. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Grant S. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Kim W. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Lee B. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Mao J. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Pera G. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 700 1- Pinnock K. Joint Science Department, Claremont McKenna, Pitzer, and Scripps Colleges, 925 N. Mills Ave., 91711, Claremont, CA, USA aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/7(2011-07-01), 1349-1360 0095-9782 40:7<1349 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer