caa a22 4500 445327901 CHVBK 20180317142727.0 cr unu---uuuuu 170323e20110701xx s 000 0 eng 10.1007/s10953-011-9710-6 doi (NATIONALLICENCE)springer-10.1007/s10953-011-9710-6 Apelblat Alexander Department of Chemical Engineering, Ben-Gurion University of the Negev, 84105, Beer Sheva, Israel aut The Representation of Electrical Conductances for Polyvalent Electrolytes by the Quint-Viallard Conductivity Equation. Part 3. Unsymmetrical 3:1, 1:3, 3:2, 4:1, 1:4, 4:2, 2:4, 1:5 1:6 and 6:1 Type Electrolytes. Dilute Aqueous Solutions of Rare Earth Salts, Various Cyanides and other Salts [Elektronische Daten] [Alexander Apelblat] Electrical conductivities of dilute aqueous solutions for unsymmetrical electrolytes of the type 3:1, 1:3, 3:2, 4:1, 1:4, 4:2, 2:4, 1:5 1:6 and 6:1 are reexamined in the framework of the Quint-Viallard conductivity equations, in order to obtain a uniform representation of their conductivities. The molar and equivalent limiting conductances were evaluated with ion association constants, which were treated as adjustable parameters. The derived values were compared with corresponding results from the literature. The following electrolytes are considered: rare earth (La,Ce,Pr,Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er) halides, perchlorides, nitrates and sulfates; hexamminecobalt and tris-ethylenediaminecobalthalides,perchlorides, nitrates and sulfates; [Ni2(trien)3]Cl4, [Pt(pn)3]Cl4, [Co2(trien)3]Cl6; cyanidesK3[Fe(CN)6], K3[Co(CN)6], M3[W(CN)8] with M=Na, K, Rb, Cs; Ca2[Fe(CN)6], K4[Fe(CN)6], K4[Mo(CN)8], K4[W(CN)8], K4[Ru(CN)8], (Me4N)4[Fe(CN)6], (Pr4N)4[Fe(CN)6],K4[Mo(CN)8],(Me4N)4[Mo(CN)8], (Et4N)4[Mo(CN)8] and (Pr4N)4[Mo(CN)8]; phosphates Na4P2O7, Na4P4O12, Na5P3O10, Na6P6O18 and (Me4N)4P4O12. Springer Science+Business Media, LLC, 2011 Electrical conductances of unsymmetric electrolytes nationallicence Limiting conductances nationallicence Ion association constants nationallicence Rare earth salts nationallicence Co nationallicence Ni nationallicence Pt organic complexes nationallicence Cyanides nationallicence Phosphates nationallicence Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/7(2011-07-01), 1291-1316 0095-9782 40:7<1291 2011 40 10953 https://doi.org/10.1007/s10953-011-9710-6 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9710-6 text/html Onlinezugriff via DOI NATIONALLICENCE 100 1- Apelblat Alexander Department of Chemical Engineering, Ben-Gurion University of the Negev, 84105, Beer Sheva, Israel aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/7(2011-07-01), 1291-1316 0095-9782 40:7<1291 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer