caa a22 4500 445328010 CHVBK 20180317142727.0 cr unu---uuuuu 170323e20111201xx s 000 0 eng 10.1007/s10953-011-9770-7 doi (NATIONALLICENCE)springer-10.1007/s10953-011-9770-7 Correlation of the Solubilizing Abilities of Hexyl(trimethyl)ammonium bis ((Trifluoromethyl)sulfonyl)imide, 1-Propyl-1-methylpiperidinium bis ((Trifluoromethyl)sulfonyl)imide, and 1-Butyl-1-methyl-pyrrolidinium Thiocyanate [Elektronische Daten] [Laura Grubbs, Shulin Ye, Mariam Saifullah, William Acree Jr., Pamela Twu, Jared Anderson, Gary Baker, Michael Abraham] Chromatographic retention data were measured for a wide range of organic solutes on 1-butyl-1-methylpyrrolidinium thiocyanate ([BMPyrr]+[SCN]−), hexyl(trimethyl)ammonium bis((trifluoromethyl)sulfonyl)imide ([HexM3Am]+[(Tf)2N]−), and 1-propyl-1-methylpiperidinium bis((trifluoromethyl)sulfonyl)imide ([PMPip]+[(Tf)2N]−) stationary phases at 323 and 353K. The measured retention factors were combined with published infinite dilution activity coefficient and gas-to-water partition coefficient data to yield gas-to-anhydrous ionic liquid (IL) partition coefficients and water-to-anhydrous IL partition coefficients. Both sets of partition coefficients were analyzed using the Abraham model. The derived Abraham model correlations describe the observed gas-to-IL and water-to-IL partition coefficient data to within average standard deviations of 0.116 and 0.156 log10 units, respectively. Springer Science+Business Media, LLC, 2011 Chromatographic retention factors nationallicence Partition coefficients nationallicence Ionic liquids nationallicence Activity coefficients nationallicence Linear free energy relationships nationallicence Grubbs Laura Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut Ye Shulin Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut Saifullah Mariam Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut Acree Jr. William Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut Twu Pamela Department of Chemistry, The University of Toledo, 2801 W. Bancroft Street MS 602, 43606, Toledo, OH, USA aut Anderson Jared Department of Chemistry, The University of Toledo, 2801 W. Bancroft Street MS 602, 43606, Toledo, OH, USA aut Baker Gary Department of Chemistry, University of Missouri-Columbia, 65211, Columbia, MO, USA aut Abraham Michael Department of Chemistry, University College London, 20 Gordon Street, WC1H 0AJ, London, UK aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/12(2011-12-01), 2000-2022 0095-9782 40:12<2000 2011 40 10953 https://doi.org/10.1007/s10953-011-9770-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9770-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Grubbs Laura Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut NATIONALLICENCE 700 1- Ye Shulin Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut NATIONALLICENCE 700 1- Saifullah Mariam Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut NATIONALLICENCE 700 1- Acree Jr William Department of Chemistry, University of North Texas, 1155 Union Circle Drive #305070, 76203-5017, Denton, TX, USA aut NATIONALLICENCE 700 1- Twu Pamela Department of Chemistry, The University of Toledo, 2801 W. Bancroft Street MS 602, 43606, Toledo, OH, USA aut NATIONALLICENCE 700 1- Anderson Jared Department of Chemistry, The University of Toledo, 2801 W. Bancroft Street MS 602, 43606, Toledo, OH, USA aut NATIONALLICENCE 700 1- Baker Gary Department of Chemistry, University of Missouri-Columbia, 65211, Columbia, MO, USA aut NATIONALLICENCE 700 1- Abraham Michael Department of Chemistry, University College London, 20 Gordon Street, WC1H 0AJ, London, UK aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/12(2011-12-01), 2000-2022 0095-9782 40:12<2000 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer