caa a22 4500 44532807X CHVBK 20180317142728.0 cr unu---uuuuu 170323e20110301xx s 000 0 eng 10.1007/s10953-011-9662-x doi (NATIONALLICENCE)springer-10.1007/s10953-011-9662-x A General Formulation Encompassing the Effects of Salts and Micelles (Direct and Reverse) on Ionic Reactions [Elektronische Daten] [María Marchena, Francisco Sánchez] Given the common behavior of ionic reactions in micellar and salt solutions and in microemulsions, a general approach has been developed for the interpretation of kinetic results in these media. This approach takes as a starting point the Brønsted equation. It has been checked by employing kinetic results for cation/cation $([\mathrm{Ru}(\mathrm{NH}_{3})_{5}\mathrm{py}^{2+}] + [\mathrm{Co}(\mathrm{NH}_{3})_{4}\mathrm{pzCO}_{2}^{2+}])$, anion/anion $(\mathrm{I}^{-}+ \mathrm{IrCl}_{6}^{2-})$ and cation/anion $([\mathrm{Ru}(\mathrm{NH}_{3})_{5}\mathrm{py}^{2+}] + \mathrm{S}_{2}\mathrm{O}_{8}^{2-})$ reactions. The approach can be easily generalized to cases in which more than two pseudophases (or more than one receptor) are present in the reactive system, as well as cases in which the reaction can follow more than two reaction paths. The approach is consistent with (but more general than) the Pseudophase and related models, such as the Pseudophase Ion Exchange Model. Springer Science+Business Media, LLC, 2011 Bronsted equation nationallicence Micellar nationallicence Microemulsions nationallicence Salt effect nationallicence Pseudophase model nationallicence Marchena María Department of Physical Chemistry, University of Seville, C/O Prof. Garcia Gonzalez, s/n, 41012, Sevilla, Spain aut Sánchez Francisco Department of Physical Chemistry, University of Seville, C/O Prof. Garcia Gonzalez, s/n, 41012, Sevilla, Spain aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/3(2011-03-01), 357-376 0095-9782 40:3<357 2011 40 10953 https://doi.org/10.1007/s10953-011-9662-x text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9662-x text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Marchena María Department of Physical Chemistry, University of Seville, C/O Prof. Garcia Gonzalez, s/n, 41012, Sevilla, Spain aut NATIONALLICENCE 700 1- Sánchez Francisco Department of Physical Chemistry, University of Seville, C/O Prof. Garcia Gonzalez, s/n, 41012, Sevilla, Spain aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/3(2011-03-01), 357-376 0095-9782 40:3<357 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer