caa a22 4500 445328169 CHVBK 20180317142728.0 cr unu---uuuuu 170323e20110301xx s 000 0 eng 10.1007/s10953-011-9657-7 doi (NATIONALLICENCE)springer-10.1007/s10953-011-9657-7 Densities, Viscosities, Speeds of Sound, FT-IR and 1H-NMR Studies of Binary Mixtures of n -Butyl Acetate with Ethanol, Propan-1-ol, Butan-1-ol and Pentan-1-ol at298.15, 303.15, 308.15 and 313.15K [Elektronische Daten] [Mehdi Hasan, Apoorva Hiray, Ujjan Kadam, Dinesh Shirude, Keshav Kurhe, Arun Sawant] Densities, viscosities and speeds of sound of binary mixtures of ethanol, propan-1-ol, butan-1-ol and pentane-1-ol with n-butyl acetate have been measured over the entire range of composition at temperatures of 298.15, 303.15, 308.15 and 313.15K and atmospheric pressure. From the experimental densities, viscosities and speeds of sound, the excess molar volumes V E, deviations in viscosity Δη, and deviations in isentropic compressibility Δκ S have been calculated. The excess molar volumes and deviations in isentropic compressibility are positive for all the binary systems studied over the whole composition, while deviations in viscosities are negative for all of the binary mixtures. The excess molar volumes, deviations in viscosity, and deviations in isentropic compressibility have been fitted to a Redlich-Kister type polynomial equation. FTIR and 1H-NMR studies of these mixtures are also reported. Springer Science+Business Media, LLC, 2011 Density nationallicence Viscosity nationallicence Speed of sound nationallicence IR nationallicence 1H-NMR nationallicence n -Butyl acetate nationallicence Alkanols nationallicence Hasan Mehdi P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut Hiray Apoorva P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut Kadam Ujjan P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut Shirude Dinesh Arts, Science and Commerce College, Nampur, India aut Kurhe Keshav Arts, Science and Commerce College, Nampur, India aut Sawant Arun P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/3(2011-03-01), 415-429 0095-9782 40:3<415 2011 40 10953 https://doi.org/10.1007/s10953-011-9657-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9657-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Hasan Mehdi P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut NATIONALLICENCE 700 1- Hiray Apoorva P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut NATIONALLICENCE 700 1- Kadam Ujjan P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut NATIONALLICENCE 700 1- Shirude Dinesh Arts, Science and Commerce College, Nampur, India aut NATIONALLICENCE 700 1- Kurhe Keshav Arts, Science and Commerce College, Nampur, India aut NATIONALLICENCE 700 1- Sawant Arun P.G. Department of Physical Chemistry, M.S.G. College, Malegaon Camp, 423 105, Pin, India aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/3(2011-03-01), 415-429 0095-9782 40:3<415 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer