caa a22 4500 44532841X CHVBK 20180317142729.0 cr unu---uuuuu 170323e20110901xx s 000 0 eng 10.1007/s10953-011-9681-7 doi (NATIONALLICENCE)springer-10.1007/s10953-011-9681-7 Facilitated Proton Transfer by a Novel 2-Aminothiazole Derivative Across the Water/1,2-Dichloroethane Interface [Elektronische Daten] [Haluk Bingol, Ahmet Coskun] The behavior of proton transfer facilitated by a novel thiazole derivative, N-methyl-4-(4-phenoxyphenyl)thiazol-2-amine (MPPT), across the water/1,2-dichloroethane (1,2-DCE) interface was investigated electrochemically. The ionic partition diagram for MPPT was obtained from interpretation of the cyclic voltammograms. The apparent partition coefficient of MPPT was evaluated by the shaking-flask method under experimental conditions, while that for the protonated form of MPPT was calculated from its transfer potential obtained from the ionic partition diagram. It was suggested that the mechanism for transfer of MPPT across the water/1,2-DCE) interface depends on the pH of the aqueous phase. The parameters of the facilitated proton transfer across the water/1,2-DCE interface were evaluated as a quantitative measure of its lipophilicity. Springer Science+Business Media, LLC, 2011 Proton transfer nationallicence Thiazole nationallicence ITIES nationallicence Ionic partition diagram nationallicence Cyclic voltammetry nationallicence Lipophilicity nationallicence Bingol Haluk Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey aut Coskun Ahmet Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/8(2011-09-01), 1505-1515 0095-9782 40:8<1505 2011 40 10953 https://doi.org/10.1007/s10953-011-9681-7 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9681-7 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Bingol Haluk Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey aut NATIONALLICENCE 700 1- Coskun Ahmet Chemistry Department, Selcuk University, 42099, Meram/Konya, Turkey aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/8(2011-09-01), 1505-1515 0095-9782 40:8<1505 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer