caa a22 4500 445328436 CHVBK 20180317142729.0 cr unu---uuuuu 170323e20110901xx s 000 0 eng 10.1007/s10953-011-9728-9 doi (NATIONALLICENCE)springer-10.1007/s10953-011-9728-9 The Dissolution Properties of 2-(1,1-Dinitromethylene)-1,3-diazepentane in N-methyl Pyrrolidone [Elektronische Daten] [Xiaoling Xing, Fengqi Zhao, Liang Xue, Kangzhen Xu, Jianhua Yi, Rongzu Hu] The dissolution properties of 2-(1,1-dinitromethylene)-1,3-diazepentane in N-methyl pyrrolidone(NMP) were studied with a RD496-2000 Calvet microcalorimeter at three different temperatures. The measured molar enthalpies (Δsol H) for 2-(1,1-dinitromethylene)-1,3-diazepentane in NMP at T=(298.15,306.15,311.15)K are (5.02, 5.59, 6.67) kJ⋅mol−1, respectively. The differential molar enthalpies (Δdif H), the specific enthalpies (Δsol h), and the standard heat effect (Q Θ) for 2-(1,1-dinitromethylene)-1,3-diazepentane in NMP were obtained at the same time. The kinetic parameters of activation energy E and pre-exponential factor A are 2.26×104J⋅mol−1 and 102.06s−1, which indicate that NMP is a good solvent for the title compound. Springer Science+Business Media, LLC, 2011 2-(1,1-Dinitromethylene)-1,3-diazepentane nationallicence NMP nationallicence Calvet microcalorimeter nationallicence Dissolution nationallicence Kinetics nationallicence Xing Xiaoling National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut Zhao Fengqi National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut Xue Liang National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut Xu Kangzhen National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut Yi Jianhua National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut Hu Rongzu National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/8(2011-09-01), 1427-1434 0095-9782 40:8<1427 2011 40 10953 https://doi.org/10.1007/s10953-011-9728-9 text/html Onlinezugriff via DOI 1 research-article jats NATIONALLICENCE 856 40 https://doi.org/10.1007/s10953-011-9728-9 text/html Onlinezugriff via DOI NATIONALLICENCE 700 1- Xing Xiaoling National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut NATIONALLICENCE 700 1- Zhao Fengqi National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut NATIONALLICENCE 700 1- Xue Liang National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut NATIONALLICENCE 700 1- Xu Kangzhen National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut NATIONALLICENCE 700 1- Yi Jianhua National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut NATIONALLICENCE 700 1- Hu Rongzu National Key Lab of Science and Technology on Propellant and Explosive Combustion, Xi'an Modern Chemistry Research Institute, 710065, Xi'an, P.R. China aut NATIONALLICENCE 773 0- Journal of Solution Chemistry Springer US; http://www.springer-ny.com 40/8(2011-09-01), 1427-1434 0095-9782 40:8<1427 2011 40 10953 Metadata rights reserved Springer special CC-BY-NC licence nationallicence BK010053 XK010053 XK010000 NATIONALLICENCE NATIONALLICENCE NL-springer